byproducts: HCl; 450°C, sealed tube; cooling to room temp. over 12 h yields crystals, evapn. of volatile products, boraadamantane is sublimated in vac,, elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 367, p. 19 - 26
chloroform in chloroform
heating of 5-Cl-2,4-C2B5H6 and CH3Cl in a react. vessel at 126°Cfor 21.0 h; further products; cold-column vac. fractionation at -104 to -29°C; identification by (11)B-NMR;
chlorine in neat (no solvent)
addn. of mixt. of B-compds. to NMR tube contg. freshly sublimed AlCl3, addn. of Cl2 gas, warmed from -190°C to room temp., kept for 7 d; not isolated; detected by NMR;
参考文献
Nam, Wonwoo; Onak, Thomas
Inorganic Chemistry, 1987 , vol. 26, p. 1581 - 1586
aluminium trichloride in neat (no solvent)
addn. of B-compds. to NMR tube contg. freshly sublimed AlCl3, addn. of C2H5Cl, sealed, warmed form -190°C to room temp., kept for 8 d; not isolated; detected by NMR;
参考文献
Nam, Wonwoo; Onak, Thomas
Inorganic Chemistry, 1987 , vol. 26, p. 1581 - 1586
