三氟乙酸2,2,2-三氟乙酯合成路线 (共 21 条)
反应条件
in toluene CF3CO2Ph added to CoH(N2)(PPh3)3 in toluene in vac., reacted for 1 h at room temp.; liquid phase analysed by GLC; hexane added, ppt. filtered, washed with hexane, dried in vac., recrystd. from C6H6-hexane;
参考文献
Hayashi, Yoshinori; Yamamoto, Takakazu; Yamamoto, Akio; Komiya, Sanshiro; Kushi, Yoshihiko
Journal of the American Chemical Society, 1986 , vol. 108, # 3 p. 385 - 391
反应条件
1.) reflux, 5 h, 2.) RT, overnight;
参考文献
Strazzolini, Paolo; Verardo, Giancarlo; Giumanini, Angelo G.
Journal of Organic Chemistry, 1988 , vol. 53, # 14 p. 3321 - 3325
反应条件
synthetic air; chlorine radical T=24.84°C; P=759.826 Torr; Kinetics; Further Variations:Reagents;
参考文献
Oyaro, Nathan; Sellevag, Stig R.; Nielsen, Claus J.
Environmental Science and Technology, 2004 , vol. 38, # 21 p. 5567 - 5576
反应条件
cesium fluoride 12 h; Ambient temperature;
参考文献
Majid,A.; Shreeve,J.M.
Journal of Organic Chemistry, 1973 , vol. 38, # 23 p. 4028 - 4031
反应条件
chlorine Irradiation.UV-Licht;
参考文献
Ben-David, Haviv; Iron, Mark A.; Neumann, Ronny
Chemical Communications, 2013 , vol. 49, # 17 p. 1720 - 1722
反应条件
platinum Hydrogenation.unter Druck;
参考文献
Swarts
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1933 , vol. 197, p. 1264
Bulletin des Societes Chimiques Belges, 1934 , vol. 43, p. 472,479
反应条件
P=33097.9 - 36775.4 Torr; Behandeln mit Eiswasser.Hydrogenation;
参考文献
Henne; Alm; Smook
Journal of the American Chemical Society, 1948 , vol. 70, p. 1968
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Swarts
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1933 , vol. 197, p. 1264
Bulletin des Societes Chimiques Belges, 1934 , vol. 43, p. 472,479
参考文献
Swarts
Bulletin des Societes Chimiques Belges, 1934 , vol. 43, p. 480
Chem. Zentralbl., 1935 , vol. 106, # I p. 549
反应条件
T=200 - 300°C; P=0.01 Torr; 0.75 h; Product distributionMechanism;
参考文献
Pellerite, Mark J.
Journal of Fluorine Chemistry, 1990 , vol. 49, # 1 p. 43 - 66
参考文献
Groth
Journal of Organic Chemistry, 1951 , vol. 24, p. 1709,1711