(Z)-3-氰基丁-2-烯酸乙酯合成路线 （共 4 条）
反应条件
palladium 10 on activated carbon; hydrogen in tetrahydrofuran T=20°C; P=760.051 Torr;
参考文献
Winkler, Christoph K.; Clay, Dorina; Davies, Simon; O'Neill, Pat; McDaid, Paul; Debarge, Sebastien; Steflik, Jeremy; Karmilowicz, Mike; Wong, John W.; Faber, Kurt
Journal of Organic Chemistry, 2013 , vol. 78, # 4 p. 1525 - 1533
反应条件
tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide
T=70°C; 15 h; Inert atmosphere;
参考文献
Winkler, Christoph K.; Clay, Dorina; Davies, Simon; O'Neill, Pat; McDaid, Paul; Debarge, Sebastien; Steflik, Jeremy; Karmilowicz, Mike; Wong, John W.; Faber, Kurt
Journal of Organic Chemistry, 2013 , vol. 78, # 4 p. 1525 - 1533
反应条件
1.1: tetreamethyl ammonium hydroxide / water; n-heptane / 0.75 h / 0 °C
1.2: 2 h / 0 °C
2.1: tetrakis(triphenylphosphine) palladium(0) / N,N-dimethyl-formamide / 15 h / 70 °C / |Inert atmosphere
View Scheme
参考文献
Winkler, Christoph K.; Clay, Dorina; Davies, Simon; O'Neill, Pat; McDaid, Paul; Debarge, Sebastien; Steflik, Jeremy; Karmilowicz, Mike; Wong, John W.; Faber, Kurt
Journal of Organic Chemistry, 2013 , vol. 78, # 4 p. 1525 - 1533
参考文献
Mowry; Rossow
Journal of the American Chemical Society, 1945 , vol. 67, p. 927
