(S)-(+)-1-氯-2-甲基丁烷合成路线 （共 15 条）
参考文献
Nozakura,S. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1673 - 1678
反应条件
phosphorus pentachloride
参考文献
Chardin; Sikorsky
Chem. Zentralbl., 1908 , vol. 79, # I p. 2143
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Marckwald
Chemische Berichte, 1901 , vol. 34, p. 479
Chemische Berichte, 1902 , vol. 35, p. 1597
反应条件
1: 1) Mg, 2) bis(diphenylphosphino)nickel(II) / diethyl ether / 20 h / Heating 2: 1) ozonized oxygen, 2) 10percent aq. NaOH, 36percent H2O2 / 1) pentane, 0 deg C, 10 h, 2) ethanol, reflux, 24 h View Scheme
参考文献
Kirmse,W.; Gruber,W.
Chemische Berichte, 1973 , vol. 106, p. 1365 - 1375
反应条件
etheric alkyl magnesium chloride
参考文献
Wiberg; Rowland
Journal of the American Chemical Society, 1955 , vol. 77, p. 1159,1162
反应条件
(i) Mg, (ii) /BRN= 1209228/; Multistep reaction;
参考文献
Nozakura,S. et al.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1673 - 1678
反应条件
(i) Mg, (ii) /BRN= 605632/, Ni(Ph2PCH2CH2CH2PPh2)Cl2; Multistep reaction;
参考文献
Tamao,K. et al.
Journal of the American Chemical Society, 1972 , vol. 94, p. 9268 - 9269
反应条件
sulfuryl dichloride; dibenzoyl peroxide Nebenprod.: 1-Chlor-2-chlormethyl-butan; dextrorotatory substance;
参考文献
Brown; Kharasch; Chao
Journal of the American Chemical Society, 1940 , vol. 62, p. 3437 - 3439
反应条件
sulfuryl dichloride; dibenzoyl peroxide Nebenprod.: 1-Chlor-2-chlormethyl-butan; levorotatory form;
参考文献
Brown; Kharasch; Chao
Journal of the American Chemical Society, 1940 , vol. 62, p. 3437 - 3439
反应条件
T=0°C; unter Belichtung; Produkt 5: linksdrehendes 1.4-Dichlor-2-methyl-butan; Produkt 6: 1-Chlor-2-chlormethyl-butan;
参考文献
Brown; Kharasch; Chao
Journal of the American Chemical Society, 1940 , vol. 62, p. 3437 - 3439
反应条件
T=80°C; Produkt 5: linksdrehendes 1.4-Dichlor-2-methyl-butan; Produkt 6: 1-Chlor-2-chlormethyl-butan;
参考文献
Brown; Kharasch; Chao
Journal of the American Chemical Society, 1940 , vol. 62, p. 3437 - 3439
