1-(3,4-二甲氧基苯基)-2-(甲基氨基)乙酮盐酸盐合成路线 （共 14 条）
反应条件
1: With hydrogen; 5-palladium/activated carbon in water T=75°C; P=2585.81 Torr; 16 - 40 h; 2: With sodium hydroxide in water; toluene pH=12; Product distribution / selectivity;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 6 ;
反应条件
1: With hydrogen; ammonium chloride; AlCl3, aluminium chloride; palladium 10 on activated carbon in water T=62 - 70°C; P=2585.81 Torr; 42 h; 2: With 4.5-0.5 Pd-Ru/C in water 3: With sodium hydroxide; ammonium chloride Product distribution / selectivity; more than 3 stages;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 7-8 ;
反应条件
1: With hydrogen; ammonium chloride; AlCl3, aluminium chloride; 5-palladium/activated carbon in water T=65 - 85°C; P=2585.81 Torr; 42 h; 2: With sodium hydroxide in water; toluene pH=12; 3: With hydrogenchloride in acetone T=5 - 15°C; Product distribution / selectivity;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
1: With hydrogen; 5-palladium/activated carbon in water T=75°C; 16 - 40 h; 2: With hydrogen; AlCl3, aluminium chloride in water P=2585.81 Torr; 20 - 105 h; 3: With hydrogenchloride; sodium hydroxide Product distribution / selectivity; more than 3 stages;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 6 ;
反应条件
1: With hydrogen; 5-palladium/activated carbon in water T=75°C; 24 h; 2: With hydrogenchloride; hydrogen in water 19 - 96 h; Product distribution / selectivity;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 7-8 ;
反应条件
1: With hydrogen; ammonium chloride; AlCl3, aluminium chloride; palladium 10 on activated carbon in water T=62 - 70°C; P=2585.81 Torr; 42 h; 2: With 4.5-0.5 Pd-Ru/C in water 3: With sodium hydroxide; ammonium chloride Product distribution / selectivity; more than 3 stages;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 7-8 ;
反应条件
1: With hydrogen; ammonium chloride; AlCl3, aluminium chloride; 5-palladium/activated carbon in water T=65 - 85°C; P=2585.81 Torr; 42 h; 2: With sodium hydroxide in water; toluene pH=12; 3: With hydrogenchloride in acetone T=5 - 15°C; Product distribution / selectivity;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
hydrogenchloride; aluminium trichloride; nitrobenzene
anschliessendes Erwaermen mit H2O;
参考文献
Moed et al.
Recueil des Travaux Chimiques des Pays-Bas, 1952 , vol. 71, p. 933,940
Recueil des Travaux Chimiques des Pays-Bas, 1955 , vol. 74, p. 919,922, 933
反应条件
1: With hydrogenchloride; methoxybenzene; AlCl3, aluminium chloride in nitrobenzene
T=25°C; 6 h; Houben-Hoesch reaction;
2: With water in nitrobenzene
T=75°C; Product distribution / selectivity;
参考文献
ALBANI, Davide; Arosio, Roberto; Merli, Valeriano
Patent: US2009/171110 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
ethanol; palladium
Hydrogenation;
参考文献
Vaughan; Blodinger
Journal of the American Chemical Society, 1955 , vol. 77, p. 5757,5759
