(R)-(-)-2-对甲苯磺酸-1-苯基-1,2-乙二醇合成路线 （共 13 条）
反应条件
formic acid; triethyl amine hydrochloride; triethylamine; Rh-(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine in ethyl acetate T=20°C; 4 h; Product distribution / selectivity;
参考文献
Lee, Do-Min; Kumaraswamy, Gullapalli; Lee, Kee-In
Monatshefte fur Chemie, 2009 , vol. 140, # 1 p. 73 - 78
反应条件
pyridine T=-10°C; 4 h;
参考文献
Uccello-Barretta, Gloria; Cuzzola, Angela; Balzano, Federica; Menicagli, Rita; Iuliano, Anna; Salvadori, Piero
Journal of Organic Chemistry, 1997 , vol. 62, # 4 p. 827 - 835
反应条件
1: 73 percent / acetonitrile / 2 h / Heating 2: (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine; HCO2H; Et3N / [Rh(C5Me5)Cl2]2 / 20 °C View Scheme
参考文献
Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin
Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806
反应条件
1: 94 percent / acetonitrile / 20 °C 2: 73 percent / acetonitrile / 2 h / Heating 3: (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine; HCO2H; Et3N / [Rh(C5Me5)Cl2]2 / 20 °C View Scheme
参考文献
Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin
Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806
反应条件
formic acid; triethylamine; (1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine; [(.eta.5-C5Me5)2Rh2Cl4] T=20°C; Title compound not separated from byproducts;
参考文献
Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin
Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806
反应条件
1: BH3*THF / tetrahydrofuran / 5 h / Ambient temperature 2: pyridine / 4 h / -10 °C View Scheme
参考文献
Mizuno, Masashi; Kanai, Motomu; Iida, Akira; Tomioka, Kiyoshi
Tetrahedron, 1997 , vol. 53, # 31 p. 10699 - 10708
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=20°C; Title compound not separated from byproducts;
参考文献
Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin
Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=20°C; Title compound not separated from byproducts;
参考文献
Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin
Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806
反应条件
lithium aluminium tetrahydride in tetrahydrofuran 3 h; Ambient temperature;
参考文献
Mangold, James B.; Abdel-Monem, Mahmoud M.
Journal of Medicinal Chemistry, 1983 , vol. 26, # 1 p. 66 - 71
反应条件
triethylamine; (1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine; [Ru2(p-PriC6H4Me)2(μ-Cl)Cl]2 T=28°C;
参考文献
Cross, David J.; Kenny, Jennifer A.; Houson, Ian; Campbell, Lynne; Walsgrove, Tim; Wills, Martin
Tetrahedron Asymmetry, 2001 , vol. 12, # 12 p. 1801 - 1806
