2,2',6,6'-四甲基联苯合成路线 （共 23 条）
反应条件
tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate in tetrahydrofuran
Suzuki coupling; 24 h; Inert atmosphereReflux;
参考文献
Teo, Shihui; Weng, Zhiqiang; Hor, T.S. Andy
Journal of Organometallic Chemistry, 2011 , vol. 696, # 17 p. 2928 - 2934
反应条件
sodium hydroxide in water
T=120 - 130°C; Microwave irradiation;
参考文献
Nasir Baig; Varma, Rajender S.
Green Chemistry, 2013 , vol. 15, # 2 p. 398 - 417
反应条件
potassium phosphate; R-Phos; bis(dibenzylideneacetone)-palladium(0) in 1,4-dioxane
T=100°C; Suzuki-Miyaura reaction; 0.333333 h; Inert atmosphere;
参考文献
Hoshi, Takashi; Nakazawa, Taichi; Saitoh, Ippei; Mori, Ayako; Suzuki, Toshio; Sakai, Jun-Ichi; Hagiwara, Hisahiro
Organic Letters, 2008 , vol. 10, # 10 p. 2063 - 2066
反应条件
potassium phosphate; R-Phos; bis(dibenzylideneacetone)-palladium(0) in 1,4-dioxane
T=100°C; Suzuki-Miyaura reaction; 2 h; Inert atmosphere;
参考文献
Hoshi, Takashi; Nakazawa, Taichi; Saitoh, Ippei; Mori, Ayako; Suzuki, Toshio; Sakai, Jun-Ichi; Hagiwara, Hisahiro
Organic Letters, 2008 , vol. 10, # 10 p. 2063 - 2066
反应条件
1: With n-butyllithium in diethyl ether; hexane
T=-78°C; 1.5 h; Inert atmosphere;
2: With copper (I) cyanide in diethyl ether; hexane
T=20°C; Inert atmosphere;
3: With DAQ in diethyl ether; hexane
4 h; Inert atmosphere;
参考文献
Shukla, Ruchi; Rathore, Rajendra
Synthesis, 2008 , # 23 art. no. M03908S, p. 3769 - 3774
反应条件
lithium perchlorate; potassium carbonate; platinum; mercury in acetonitrile
T=0°C; 3 h; Electrochemical reaction;
参考文献
Barba, Fructuoso; Batanero, Belen; Tissaoui, Khalil; Raouafi, Noureddine; Boujlel, Khaled
Electrochemistry Communications, 2010 , vol. 12, # 7 p. 973 - 976
反应条件
palladium diacetate; BIPHEP; copper(l) chloride in N,N-dimethyl-formamide
T=80°C; 14 h; Inert atmosphere;
参考文献
Li, Gao-Qiang; Yamamoto, Yasunori; Miyaura, Norio
Synlett, 2011 , # 12 p. 1769 - 1773
反应条件
[Pd(1,3-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene)(cinnamyl)Cl]; potassium 2-methyl-2-butoxide in 1,4-dioxane
T=110°C; Buchwald-Hartwig Coupling; 12 h; Inert atmosphereSealed tube;
参考文献
Bastug, Gulluzar; Nolan, Steven P.
Organometallics, 2014 , vol. 33, # 5 p. 1253 - 1258
反应条件
palladium on activated charcoal; 1,8-diazabicyclo[5.4.0]undec-7-ene in acetonitrile
T=80°C; 20 h; Autoclave;
参考文献
Yu, Bo; Zhao, Yanfei; Zhang, Hongye; Xu, Jilei; Hao, Leiduan; Gao, Xiang; Liu, Zhimin
Chemical Communications, 2014 , vol. 50, # 18 p. 2330 - 2333
反应条件
copper
T=240 - 265°C;
参考文献
Carlin
Journal of the American Chemical Society, 1945 , vol. 67, p. 928,931
