[Ir(C8H12)(OCH3)]2; 4,4'-di-tertbutylpyridine in further solvent(s)
(N2); heating mixt. of iridium compd., bipyridine deriv., benzene deriv., dodecane and silylborane deriv. at 80°C for 4 h; cooling to room temp., chromy. (silica gel, diethyl ether in hexane (gradient from 0percent to 5percent)), NMR;
参考文献
Boebel, Timothy A.; Hartwig, John F.
Organometallics, 2008 , vol. 27, # 22 p. 6013 - 6019
in perdeuterocyclohexane
(Schlenk; N2 atm.) a soln. of complex and cyclooctene in cyclohexane-d12and methylcyclohexane-d14 was reacted with 20 equiv of (CF3)2C6H4 at 0. degree.C; detected by NMR spectra;
参考文献
Boller, Timothy M.; Murphy, Jaclyn M.; Hapke, Marko; Ishiyama, Tatsuo; Miyaura, Norio; Hartwig, John F.
Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14263 - 14278
in perdeuterocyclohexane
Kinetics; at 25°C for 48 h; detd. by 1H and 31P NMR;
参考文献
Chotana, Ghayoor A.; Vanchura II, Britt A.; Tse, Man Kin; Staples, Richard J.; Maleczka Jr., Robert E.; Smith III, Milton R.
Chemical Communications, 2009 , # 38 p. 5731 - 5733
n-butyllithium in diethyl ether; hexane
T=-78 - 20°C; 4 h;
参考文献
Cornet, Stephanie M.; Dillon, Keith B.; Entwistle, Christopher D.; Fox, Mark A.; Goeta, Andres E.; Goodwin, Helen P.; Marder, Todd B.; Thompson, Amber L.
Dalton Transactions, 2003 , # 23 p. 4395 - 4405
in neat (no solvent)
condensation at -196°C of Cr vapor (obtained by heating of solid)with equimolar mixt. of arenes; evapn. (reduced pressure), dissoln. in hexane at room temp., evapn., sublimation (vac.); product mixt. not sepd., detd. by mass spectroscopy;
参考文献
Seeley, Andrew J.; Hudson, Simon; Sykes, Paul D.; Weise, W. Burkhard; Timms, Peter L.
Journal of Organometallic Chemistry, 1995 , vol. 487, # 1-2 p. 167 - 172
