3,5-双三氟甲基苯甲醛合成路线 （共 36 条）
反应条件
hydrogen; quinoline; 5 palladium on barium sulfate; sulfur in toluene T=100 - 110°C; 12 h;
参考文献
BAYER AG
Patent: EP1191012 A1, 2002 ;
Location in patent: Page 4 ;
反应条件
hydrogenchloride; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; sodium nitrite in dichloromethane; water T=20°C; P=760.051 Torr; 12 h; in air;
参考文献
Wang, Xinliang; Liu, Renhua; Jin, Yu; Liang, Xinmiao
Chemistry - A European Journal, 2008 , vol. 14, # 9 p. 2679 - 2685
反应条件
hydrogen sulfide; palladium in quinoline; water; toluene
参考文献
Baumann, Kathe; Marhold, Albrecht
Patent: US2002/38055 A1, 2002 ;
反应条件
formic acid; hydrogen; Raney nickel in water T=70°C; P=13501.4 Torr; 10 h;
参考文献
Bayer Chemicals AG
Patent: EP1389608 A1, 2004 ;
Location in patent: Page/Page column 5 - 6 ;
反应条件
sodium formate; bis(triphenylphosphine)palladium(II) chloride in CO; N,N-dimethyl-formamide
参考文献
Bayer Aktiengesellschaft
Patent: US6462242 B1, 2002 ;
反应条件
n-butyllithium in diethyl ether
参考文献
Porwisiak, Jacek; Schlosser, Manfred
Chemische Berichte, 1996 , vol. 129, # 2 p. 233 - 235
反应条件
lithium perchlorate in water; acetonitrile 17 h; Electrochemical reaction;
参考文献
Wu, Xin; Davis, Anthony P.; Fry, Albert J.
Organic Letters, 2007 , vol. 9, # 26 p. 5632 - 5636
反应条件
(i) SOCl2, (ii) Li<AlH(OtBu)3>, diglyme; Multistep reaction;
参考文献
Blackburn, Christopher; Childs, Ronald F.; Cremer, Dieter; Gauss, Juergen
Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2442 - 2448
参考文献
Cytovia, Inc.
Patent: US2003/13743 A1, 2003 ;
US 20030013743 A1
反应条件
1: 87 percent / 96percent H2SO4, N,N'-dibromo-5,5-dimethylhydantoin / 24 h / 0 °C 2: 82 percent / BuLi / diethyl ether View Scheme
参考文献
Porwisiak, Jacek; Schlosser, Manfred
Chemische Berichte, 1996 , vol. 129, # 2 p. 233 - 235
