1,3-戊二炔-1-基苯合成路线 （共 24 条）
反应条件
[PhCW{OSi(OtBu)3}3] in 1,2,4-trichloro-benzene T=20°C;
参考文献
Lysenko, Sergej; Volbeda, Jeroen; Jones, Peter G.; Tamm, Matthias
Angewandte Chemie - International Edition, 2012 , vol. 51, # 27 p. 6757 - 6761
反应条件
in hexane Irradiation;
参考文献
Kwon, Jang Hyuk; Lee, Sang Jin; Shim, Sang Chul
Tetrahedron Letters, 1991 , vol. 32, # 46 p. 6719 - 6722
参考文献
Kwon, Jang Hyuk; Lee, Sang Jin; Shim, Sang Chul
Tetrahedron Letters, 1991 , vol. 32, # 46 p. 6719 - 6722
反应条件
hydrazine hydrate in ethanol T=75 - 78°C; 8.5 h;
参考文献
Khrimyan, A. P.; Karapetyan, A. V.; Badanyan, Sh. O.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1984 , vol. 20, # 2 p. 189 - 196
Khimiya Geterotsiklicheskikh Soedinenii, 1984 , vol. 20, # 2 p. 230 - 238
反应条件
[PhCW{OSi(OtBu)3}3] in toluene T=20°C; 2 h; Molecular sieve;
参考文献
Lysenko, Sergej; Volbeda, Jeroen; Jones, Peter G.; Tamm, Matthias
Angewandte Chemie - International Edition, 2012 , vol. 51, # 27 p. 6757 - 6761
反应条件
[PhCW{OSi(OtBu)3}3] in 1,2,4-trichloro-benzene T=20°C;
参考文献
Lysenko, Sergej; Volbeda, Jeroen; Jones, Peter G.; Tamm, Matthias
Angewandte Chemie - International Edition, 2012 , vol. 51, # 27 p. 6757 - 6761
反应条件
1: (E)-1-(4-chlorobut-3-en-1-ynyl)benzene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h;
2: methyl iodide in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Metay, Estelle; Hu, Qian; Negishi, Ei-Ichi
Organic Letters, 2006 , vol. 8, # 25 p. 5773 - 5776
反应条件
1: (1-dibromomethylene-prop-2-ynyl)-benzene With n-butyllithium in hexane; toluene
T=-20 - 0°C; Fritsch-Buttenberg-Wiechell rearrangement;
2: methyl iodide in diethyl ether; hexane; toluene
T=-20 - 20°C; Further stages.;
参考文献
Luu, Thanh; Morisaki, Yasuhiro; Tykwinski, Rik R.
Synthesis, 2008 , # 7 p. 1158 - 1162
反应条件
potassium 2,6-di(tert-butyl)phenolate in ethylene glycol dimethyl ether
T=50 - 55°C; 0.5 h;
参考文献
Stang, Peter J.; Dixit, Vandana
Synthesis, 1985 , # 10 p. 962 - 963
参考文献
Groizeleau-Miginiac
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959 , vol. 248, p. 1190,1191
Annales de Chimie (Cachan, France), 1961 , vol. <13>6, p. 1071,1099,1102
