1-溴-2,4,6-三叔丁基苯合成路线 （共 38 条）
反应条件
bromine in various solvent(s) T=75°C; Bromination; 96 h;
参考文献
Look, Kai; Norris, Robert K.
Australian Journal of Chemistry, 1999 , vol. 52, # 11 p. 1077 - 1083
反应条件
bromine in various solvent(s) 72 h; 4 mol excess of Br2;
参考文献
Davis, Franklin A.; Jenkins, Robert H.; Rizvi, Syed Q. A.; Yocklovich, Steven G.
Journal of Organic Chemistry, 1981 , vol. 46, # 17 p. 3467 - 3474
反应条件
hydrogenchloride in tetrahydrofuran; diethyl ether byproducts: LiCl; addn. of soln. of BrSiCl3 in THF to soln. of org.compd. in THF (-78°C), stirring (1 h, -78°C), addn. of HCl in ether; not isolated; (1)H-NMR spectrometry;
参考文献
Weiss, H.; Oehme, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 572, p. 186 - 191
反应条件
water; bromine 1.) CCl4, room temp.; Yield given. Multistep reaction;
参考文献
Yoshifuji, Masaaki; Shima, Ichiro; Shibayama, Katsuhiro; Inamoto, Naoki
Tetrahedron Letters, 1984 , vol. 25, # 4 p. 411 - 414
反应条件
hydrogen bromide; copper(I) bromide; sodium nitrite
参考文献
Betts; Barclay
Canadian Journal of Chemistry, 1955 , vol. 33, p. 1768,1769
反应条件
bromine in tetrachloromethane Ambient temperaturefurther solvent; other ratio of the reactants;; MechanismProduct distribution;
参考文献
Yoshifuji, Masaaki; Shima, Ichiro; Shibayama, Katsuhiro; Inamoto, Naoki
Tetrahedron Letters, 1984 , vol. 25, # 4 p. 411 - 414
参考文献
Betts; Barclay
Canadian Journal of Chemistry, 1955 , vol. 33, p. 1768,1769
反应条件
Yield given. Multistep reaction;
参考文献
Rundel,W.
Chemische Berichte, 1968 , vol. 101, p. 2956 - 2962
反应条件
2,2'-azo-bisisobutyronitrile in benzene T=80°C; 3 h; Rate constantMechanism;
参考文献
Crich, David; Hwang, Jae-Taeg; Gastaldi, Stephane; Recupero, Francesco; Wink, Donald J.
Journal of Organic Chemistry, 1999 , vol. 64, # 8 p. 2877 - 2882
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=0°C; 1.5 h; 2: With sulfuryl dichloride in diethyl ether; hexane T=-78 - 20°C;
参考文献
Torker, Sebastian; Mueller, Andre; Chen, Peter
Angewandte Chemie - International Edition, 2010 , vol. 49, # 22 p. 3762 - 3766
