2-甲氧基-4-甲基苯胺合成路线 （共 25 条）
反应条件
hydrogen; palladium on activated charcoal in ethanol Reduction; 1 h;
参考文献
Coleman; Guernon; Roland
Organic letters, 2000 , vol. 2, # 3 p. 277 - 280
反应条件
1: KOH; Bu4NHSO4 / toluene / 20 °C 2: H2 / Pd/C / 3 h / 20 °C View Scheme
参考文献
Haworth; Lapworth
Journal of the Chemical Society, 1923 , vol. 123, p. 2989
Journal of the Chemical Society, 1924 , vol. 125, p. 1305
反应条件
1: sulfuric acid; sodium nitrate / water / 2 h / 0 - 10 °C 2: potassium carbonate / acetone / 5 h / |Reflux 3: hydrazine hydrate / methanol / 3 h / |Reflux View Scheme
参考文献
Chakraborty, Suchandra; Chattopadhyay, Gautam; Saha, Chandan
Journal of Heterocyclic Chemistry, 2013 , vol. 50, # 1 p. 91 - 98
反应条件
sodium hydroxide; sulfur
参考文献
Khotinsky; Jacopson-Jacopmann
Chemische Berichte, 1909 , vol. 42, p. 3101
反应条件
water Erhitzen des Reaktionsprodukts mit Calciumhydroxid;
参考文献
Barclay; Burawoy; Thomson
Journal of the Chemical Society, 1944 , p. 109,111
反应条件
T=25°C; Product distribution;
参考文献
Helmick, John S.; Martin, Kristy A.; Heinrich, Julie L.; Novak, Michael
Journal of the American Chemical Society, 1991 , vol. 113, # 9 p. 3459 - 3466
反应条件
T=25°C; other O-pivaloyl-N-arylhydroxylamines; Product distributionMechanism;
参考文献
Helmick, John S.; Martin, Kristy A.; Heinrich, Julie L.; Novak, Michael
Journal of the American Chemical Society, 1991 , vol. 113, # 9 p. 3459 - 3466
参考文献
v.Auwers; Lechner; Bundesmann
Chemische Berichte, 1925 , vol. 58, p. 41
反应条件
1.1: copper(ll) bromide; tert.-butylnitrite / acetonitrile / 0.33 h / 65 °C / Inert atmosphere 2.1: tert.-butyl lithium / pentane; tetrahydrofuran / 0.17 h / -78 °C / Inert atmosphere 2.2: 2 h / -78 - 20 °C View Scheme
参考文献
KATHOLIEKE UNIVERSITEIT LEUVEN
Patent: US2012/316161 A1, 2012 ;
反应条件
tert.-butylnitrite; copper(ll) bromide in acetonitrile T=20 - 65°C; 0.25 h;
参考文献
UNIVERSITY COLLEGE LONDON
Patent: WO2005/123676 A1, 2005 ;
Location in patent: Page/Page column 36-37 ;
