1: With benzo[1,3,2]dioxaborole; rhodium complex 10 in toluene T=20°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; water; dihydrogen peroxide in toluene T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Chemistry - A European Journal, , vol. 5, # 4 p. 1320 - 1330
1: With (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl; [Rh(COD)2](1+)*BF4(1-) in ethylene glycol dimethyl ether T=-78 - 20°C; 2: With sodium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether T=0 - 20°C; 2 h; Further stages. Title compound not separated from byproducts.;
参考文献
Journal of Fluorine Chemistry, , vol. 128, # 7 p. 827 - 831
1: With benzo[1,3,2]dioxaborole; rhodium complex 10 in toluene T=20°C; Addition; Hydroboration; 2 h; 2: With sodium hydroxide; water; dihydrogen peroxide in toluene T=20°C; Oxidation; 2 h; Title compound not separated from byproducts;
参考文献
Demay, Steandphane; Volant, Florence; Knochel, Paul
Angewandte Chemie - International Edition, 2001 , vol. 40, # 7 p. 1235 - 1238
1: With (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl; [Rh(COD)2](1+)*BF4(1-) in ethylene glycol dimethyl ether T=-78 - 20°C; 2: With sodium hydroxide; dihydrogen peroxide in ethylene glycol dimethyl ether T=0 - 20°C; 2 h; Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.
Journal of Fluorine Chemistry, 2007 , vol. 128, # 7 p. 827 - 831
[rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen; (R,S)-Binaphos in benzene T=40°C; P=76000 Torr; 30 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Nozaki, Kyoko; Sakai, Nozomu; Nanno, Tetsuo; Higashijima, Takanori; Mano, Satoshi; Horiuchi, Toshihide; Takaya, Hidemasa
Journal of the American Chemical Society, 1997 , vol. 119, # 19 p. 4413 - 4423
