氯(甲基二苯膦)金(I)合成路线 （共 12 条）
反应条件
in not given
byproducts: CH3(C6H5)2PO; 2 equiv. of phosphine; elem. anal.;
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in dichloromethane
byproducts: Me2S; (protection from light); removal of solvent by passing N2 over the reaction mixture, recrystn. (CH2Cl2/EtOH); elem. anal.;
参考文献
Copley, Royston C. B.; Mingos, D. Michael P.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 4 p. 479 - 489
反应条件
in neat (no solvent)
Au complex reacted with equimolar amounts of ligand;
参考文献
Cerrada, Elena; Laguna, Mariano; Lardies, Nora
European Journal of Inorganic Chemistry, 2009 , # 1 p. 137 - 146
反应条件
in not given
byproducts: PPh3;
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in dichloromethane
byproducts: TolPh2SiH; To a soln. of PPh2MeAuSiPh2Tol was added dry HCl gas under exclusion of light. After addition of petroleum ether complex crystd. at -25 °C.; washing with petroleum ether, drying in high vac., elem. anal., detected by (1)H-NMR;
参考文献
Meyer, Juergen; Willnecker, Johannes; Schubert, Ulrich
Chemische Berichte, 1989 , vol. 122, p. 223 - 230
反应条件
in dichloromethane
byproducts: TolPh2SiCl; To a soln. of PPh2MeAuSiPh2Tol was added at 0 °C under exclusion of light Cl2. After some min petroleum ether was added and complex crystd. at -25 °C.; washing with petroleum ether, drying in high vac., elem. anal., detected by (1)H-NMR;
参考文献
Meyer, Juergen; Willnecker, Johannes; Schubert, Ulrich
Chemische Berichte, 1989 , vol. 122, p. 223 - 230
反应条件
in tetrahydrofuran
byproducts: HSiMeClOAc; To a soln. of Ph2MePAuOAc in THF was added HSiMeCl2.; crystn. with petroleum ether, washing with petroleum ether, drying in high vac.;
参考文献
Meyer, Juergen; Willnecker, Johannes; Schubert, Ulrich
Chemische Berichte, 1989 , vol. 122, p. 223 - 230
反应条件
in tetrahydrofuran
byproducts: HSiPh2OAc; To a soln. of Ph2MePAuOAc in THF was added HSiPh2Cl.; crystn. with petroleum ether, washing with petroleum ether, drying in high vac.;
参考文献
Meyer, Juergen; Willnecker, Johannes; Schubert, Ulrich
Chemische Berichte, 1989 , vol. 122, p. 223 - 230
反应条件
in tetrahydrofuran
byproducts: HSiMe2OAc; To a soln. of Ph2MePAuOAc in THF was added HSiMe2Cl.; crystn. with petroleum ether, washing with petroleum ether, drying in high vac.;
参考文献
Meyer, Juergen; Willnecker, Johannes; Schubert, Ulrich
Chemische Berichte, 1989 , vol. 122, p. 223 - 230
反应条件
in not given
7 days;
参考文献
Johnson, Antony; Puddephatt, Richard J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1978 , p. 980 - 985
