反应条件
1: tris-(dibenzylideneacetone)dipalladium(0); t-Bu Brett Phos; sodium nitrite; TDA / tert-butyl alcohol / 130 °C / |Schlenk technique; |Inert atmosphere 2: indium tribromide; triethylsilane / N,N-dimethyl-formamide / 60 °C / |Schlenk technique; |Inert atmosphere 3: zinc; ammonium chloride / tetrahydrofuran / 0.5 h / 0 - 20 °C / |Schlenk technique 4: (R)-3,3′-bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate / chloroform / 66 h / -50 °C / |Inert atmosphere View Scheme
参考文献
De, Chandra Kanta; Pesciaioli, Fabio; List, Benjamin
Angewandte Chemie - International Edition, 2013 , vol. 52, # 35 p. 9293 - 9295
Angew. Chem., 2013 , vol. 125, # 35 p. 9463 - 9465,3
