3-(全氟正辛基)-1,2-环氧丙烷合成路线 （共 13 条）
反应条件
potassium carbonate; bis-triphenylphosphine-palladium(II) chloride in acetonitrile T=80°C; 6 h; various polyfluoroalkyl halides, allylic alcohols and terminal alkynes investigated; Product distribution;
参考文献
Fuchikami, Takamasa; Shibata, Yoshiko; Urata, Hisao
Chemistry Letters, 1987 , p. 521 - 524
反应条件
potassium hydroxide in hexane 5 h; Heating;
参考文献
Guyot, Bernard; Ameduri, Bruno; Boutevin, Bernard
Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 233 - 240
反应条件
potassium hydroxide in hexane 2 h; Heating; Yields of byproduct given;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
反应条件
potassium hydroxide; 2,2'-azo-bisisobutyronitrile in 1,2-dichloro-ethane T=70°C; Substitution; Cyclization; Dimerization; 2 h;
参考文献
Rubio; Blancou; Commeyras
Journal of Fluorine Chemistry, 2000 , vol. 106, # 1 p. 1 - 5
反应条件
potassium hydroxide in dichloromethane 1 h; Yield given;
参考文献
Conte; Maniero; Zaggia; Bertani; Gambaretto; Berton; Seraglia
Journal of Fluorine Chemistry, 2005 , vol. 126, # 9-10 p. 1274 - 1280
反应条件
1: aq. Na2S2O5; 2,2'-azobis(2-methylpropionitrile) / 2 h / 80 °C 2: 783.0 g / aq. NaOH / propan-2-ol / 0.75 h / 20 °C View Scheme
参考文献
Laurent, Philippe; Blancou, Hubert; Commeyras, Auguste
Journal of Fluorine Chemistry, 1993 , vol. 64, # 1-2 p. 125 - 128
反应条件
pyridine in N,N-dimethyl-formamide 1 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Umemoto, Teruo; Kuriu, Yuriko; Nakayama, Shin-ichi
Tetrahedron Letters, 1982 , vol. 23, # 11 p. 1169 - 1172
反应条件
potassium hydroxide in diethyl ether 7 h; Heating; Yields of byproduct given;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
反应条件
potassium hydroxide; 2,6-di-t-butyl-4-methyl-phenol 2.) hexane, reflux, 3 h; Yield given. Multistep reaction;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
反应条件
potassium hydroxide; 2,6-di-t-butyl-4-methyl-phenol 2.) Et2O, reflux, 7 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
