2-氯-4,6-二苯基-1,3,5-三嗪合成路线 (共 20 条)
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in water; toluene 8 h; Inert atmosphereReflux;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: EP2415769 A1, 2012 ;
Location in patent: Page/Page column 116-117 ;
反应条件
1: bromobenzene With iodine; magnesium in tetrahydrofuran T=20°C; Reflux; 2: 2,4,6-trichloro-1,3,5-triazine in tetrahydrofuran T=0 - 50°C;
参考文献
Zhong, Hongliang; Xu, Erjian; Zeng, Danli; Du, Junping; Sun, Jing; Ren, Shijie; Jiang, Biao; Fang, Qiang
Organic Letters, 2008 , vol. 10, # 5 p. 709 - 712
反应条件
in tetrahydrofuran T=0 - 20°C; 12 h;
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.; KIM, Hyun; JUNG, So-Young; KIM, Chi-Sik; PARK, Kyoung-Jin; PARK, So-Mi; LEE, Kyung-Joo; KWON, Hyuck-Joo; KIM, Bong-Ok
Patent: WO2014/3440 A1, 2014 ;
Location in patent: Paragraph 161; 162; 163; 164 ;
反应条件
hydrogenchloride in tetrahydrofuran; water; toluene
参考文献
Ciba-Geigy Corporation
Patent: US5438138 A1, 1995 ;
反应条件
phosphorus pentachloride CH3CN, 1h, reflux; Yield given. Multistep reaction;
参考文献
Harris, Roger L.N.
Synthesis, 1980 , # 10 p. 841 - 842
反应条件
thionyl chloride; phosphorus pentachloride; 1,2-dichloro-benzene T=140°C;
参考文献
Am.Cyanamid Co.
Patent: US2691018 , 1951 ;
反应条件
trichlorophosphate 1.) 5 min, 100 deg C, 2.) CH3CN, 30 min, reflux; Yield given. Multistep reaction;
参考文献
Harris, Roger L.N.
Synthesis, 1980 , # 10 p. 841 - 842
参考文献
Hirt et al.
Helvetica Chimica Acta, 1950 , vol. 33, p. 1365,1368
Full Text Show Details
Grundmann et al.
Chemische Berichte, 1953 , vol. 86, p. 181,184
反应条件
chloroform; phosphorus pentachloride
参考文献
Ruccia
Gazzetta Chimica Italiana, 1959 , vol. 89, p. 1670,1679
反应条件
in toluene 1 h; Heating; Yield given;
参考文献
Harris, Roger L. N.
Australian Journal of Chemistry, 1981 , vol. 34, # 3 p. 623 - 634