2-硝基-Alpha,Alpha,Alpha-三氟甲苯合成路线 (共 51 条)
反应条件
1: palladium / Hydrogenation 2: Bildung ueber die Diazonium-Verbindung View Scheme
参考文献
Jones
Journal of the American Chemical Society, 1947 , vol. 69, p. 2352
反应条件
1: palladium / Hydrogenation 2: Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuBr in wss. HBr View Scheme
参考文献
Jones
Journal of the American Chemical Society, 1947 , vol. 69, p. 2352
反应条件
1: H2 / Raney-Ni / petroleum ether 2: (i) NaNO2, aq. HCl, (ii) NH3, SO2 View Scheme
参考文献
Forbes,E.J. et al.
Tetrahedron, 1960 , vol. 8, p. 67 - 72
反应条件
1: palladium / Hydrogenation 2: Diazotization.Behandlung der Diazoniumsalz-Loesung mit CuCl View Scheme
参考文献
Jones
Journal of the American Chemical Society, 1947 , vol. 69, p. 2352
反应条件
1,3-dimethyl-imidazolidin-2-one; sodium trimethylsilanethiolate T=185°C; 24 h;
参考文献
Hwu, Jih Ru; Wong, Fung Fuh; Shiao, Min-Jen
Journal of Organic Chemistry, 1992 , vol. 57, # 19 p. 5254 - 5255
反应条件
1,10-phenanthroline; Pd(1,10-phenanthroline)2(OTf)2 T=135°C; P=45003.6 Torr; 2 h;
参考文献
Chemische Berichte, , vol. 130, # 1 p. 13 - 21
反应条件
bismuth; hydrogen fluoride in dichloromethane Yields of byproduct given;
参考文献
Tordeux, Marc; Wakselman, Claude
Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 251 - 254
参考文献
Rouche
Bulletin de la Classe des Sciences, Academie Royale de Belgique, 1927 , vol. <5> 13, p. 349
Chem. Zentralbl., 1927 , vol. 98, # II p. 1817
反应条件
tert.-butylhydroperoxide; potassium tert-butylate in ammonia T=-33°C;
参考文献
Journal of Organic Chemistry, , vol. 63, # 13 p. 4199 - 4208
反应条件
1: palladium / Hydrogenation 2: Bildung ueber die Diazonium-Verbindung 3: water; bromine 4: aq. NaOH solution View Scheme
参考文献
Jones
Journal of the American Chemical Society, 1947 , vol. 69, p. 2352