(R)-(+)-N-苄基-1-苯乙胺合成路线 （共 41 条）
反应条件
RuH(BH4)[(S,S)-xylskewphos][(S,S)-dpen]; hydrogen; sodium t-butanolate in toluene T=40°C; P=7600.51 Torr; 15 h; AutoclaveInert atmosphere; enantioselective reaction;
参考文献
National University Corporation Hokkaido University; Kanto Kagaku Kabushiki Kaisha; Ohkuma, Takeshi; Arai, Noriyoshi; Utsumi, Noriyuki; Murata, Kunihiko; Tsutsumi, Kunihiko
Patent: US2013/197234 A1, 2013 ;
Location in patent: Paragraph 0192 ;
反应条件
sodium tris(acetoxy)borohydride in 1,2-dichloro-ethane 1 h;
参考文献
Kuwahara, Shunsuke; Chamura, Rie; Tsuchiya, Sho; Ikeda, Mari; Habata, Yoichi
Chemical Communications, 2013 , vol. 49, # 22 p. 2186 - 2188
反应条件
(+)-2,6'-bis(diphenylphosphino)-2'-methoxy-1,1'-biphenyl; hydrogen; bis(1,5-cyclooctadiene)-di(iridium(I)-dichloride) in methanol T=20 - 30°C; P=37503.8 Torr; 18 h;
参考文献
Lonza AG
Patent: EP1609795 A1, 2005 ;
Location in patent: Page/Page column 15 ;
反应条件
1: With boron trifluoride diethyl etherate in methanol; toluene T=-5°C; 155 h; 2: With sodium hydrogencarbonate in water; toluene optical yield given as percent eeenantioselective reaction;
参考文献
Zhu, Rui-Heng; Shi, Xiao-Xin
Tetrahedron Asymmetry, 2011 , vol. 22, # 4 p. 387 - 393
反应条件
1: With boron trifluoride diethyl etherate in methanol; toluene T=-5°C; 155 h; 2: With sodium hydrogencarbonate in water; toluene optical yield given as percent eeenantioselective reaction;
参考文献
Zhu, Rui-Heng; Shi, Xiao-Xin
Tetrahedron Asymmetry, 2011 , vol. 22, # 4 p. 387 - 393
反应条件
1: With boron trifluoride diethyl etherate in methanol; toluene T=-5°C; 155 h; 2: With sodium hydrogencarbonate in water; toluene optical yield given as percent eeenantioselective reaction;
参考文献
Zhu, Rui-Heng; Shi, Xiao-Xin
Tetrahedron Asymmetry, 2011 , vol. 22, # 4 p. 387 - 393
反应条件
1: With boron trifluoride diethyl etherate in methanol; toluene T=-5°C; 155 h; 2: With sodium hydrogencarbonate in water; toluene optical yield given as percent eeenantioselective reaction;
参考文献
Zhu, Rui-Heng; Shi, Xiao-Xin
Tetrahedron Asymmetry, 2011 , vol. 22, # 4 p. 387 - 393
反应条件
anhydrous magnesium perchlorate; S-(+)-1-benzyl-3-hydroxymethyl-4-methyl-1,4-dihydropyridine in acetonitrile T=45°C; 72 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Kang, Guo-Jun; Cullen, William R.; Fryzuk, Michael D.; James, Brian R.; Kutney, James P.
Journal of the Chemical Society, Chemical Communications, 1988 , # 22 p. 1466 - 1467
反应条件
1: With boron trifluoride diethyl etherate in methanol; toluene T=-5°C; 155 h; 2: With sodium hydrogencarbonate in water; toluene optical yield given as percent eeenantioselective reaction;
参考文献
Zhu, Rui-Heng; Shi, Xiao-Xin
Tetrahedron Asymmetry, 2011 , vol. 22, # 4 p. 387 - 393
反应条件
1: With boron trifluoride diethyl etherate in methanol; toluene T=-5°C; 155 h; 2: With sodium hydrogencarbonate in water; toluene optical yield given as percent eeenantioselective reaction;
参考文献
Zhu, Rui-Heng; Shi, Xiao-Xin
Tetrahedron Asymmetry, 2011 , vol. 22, # 4 p. 387 - 393
