4-雄烯-11β-醇-3,17-二酮合成路线 （共 31 条）
反应条件
1: With sodium tetrahydroborate in ethanol; dichloromethane 2 h; 2: With sodium periodate in acetone T=20°C;
参考文献
Wuest, Frank; Carlson, Kathryn E.; Katzenellenbogen, John A.
Steroids, 2003 , vol. 68, # 2 p. 177 - 191
反应条件
zinc in N,N-dimethyl-formamide
参考文献
The Upjohn Company
Patent: US4325881 A1, 1982 ;
反应条件
in tetrahydrofuran; water
参考文献
The Upjohn Company
Patent: US4325881 A1, 1982 ;
反应条件
zinc in tetrahydrofuran; n-heptane; N,N-dimethyl-formamide
参考文献
The Upjohn Company
Patent: US5426198 A1, 1995 ;
反应条件
trifluorormethanesulfonic acid in 1,4-dioxane T=80°C;
参考文献
Pinto, Rui M. A.; Salvador, Jorge A. R.; Le Roux, Christophe; Paixao, Jose A.
Journal of Organic Chemistry, 2009 , vol. 74, # 21 p. 8488 - 8491
反应条件
D-glucose; mycelium of Curvularia lunata fungus in water 72 h;
参考文献
Shuvalova; Gabinskaya; Popova; Savinova; Andryushina
Pharmaceutical Chemistry Journal, 2001 , vol. 35, # 5 p. 279 - 281
反应条件
Nostoc muscorum PTCC 1636 in ethanol T=25°C; 168 h;
参考文献
Yazdi, Mojtaba Tabatabaei; Arabi, Homeira; Faramarzi, Mohammad Ali; Ghasemi, Younes; Amini, Mohsen; Shokravi, Shadman; Mohseni, Farzaneh Aziz
Phytochemistry, 2004 , vol. 65, # 15 p. 2205 - 2209
参考文献
Huang-Minlon; Pettebone
Journal of the American Chemical Society, 1952 , vol. 74, p. 1562
反应条件
lithium aluminium tetrahydride; diethyl ether und anschliessend mit Natriumacetat,Methanol und wss.Essigsaeure;
参考文献
Herr; Heyl
Journal of the American Chemical Society, 1953 , vol. 75, p. 5927,5929
反应条件
1: LiBH4; THF / aufeinanderfolgende Umsetzung mit Acetanhydrid in Pyridin und mit Brenztraubensaeure und Natriumacetat in wss.Essigsaeure 2: HIO4 View Scheme
参考文献
Huang-Minlon; Pettebone
Journal of the American Chemical Society, 1952 , vol. 74, p. 1562
