3-苯基环戊-2-烯-1-酮合成路线 （共 62 条）
反应条件
[Pd(1,2-bis(diphenylphosphanyl)ethane)(PhCN)2](SbF6)2; potassium carbonate in tetrahydrofuran
T=20°C; 23 h;
参考文献
Nishikata, Takashi; Yamamoto, Yasunori; Miyaura, Norio
Angewandte Chemie - International Edition, 2003 , vol. 42, # 24 p. 2768 - 2770
反应条件
n-butyllithium in diethyl ether
T=-78 - 20°C;
参考文献
Li, Zhi; Moser, William H.; Deng, Ruixue; Sun, Liangdong
Journal of Organic Chemistry, 2007 , vol. 72, # 26 p. 10254 - 10257
反应条件
trifluorormethanesulfonic acid in dichloromethane
T=20°C; Nazarov Cyclization; 5 h; Inert atmosphere; Reagent/catalyst;
参考文献
Joy, Shaon; Nakanishi, Waka; West
Tetrahedron Letters, 2013 , vol. 54, # 41 p. 5573 - 5576
反应条件
aluminum oxide in toluene
3 h; Heating;
参考文献
Kjeldsen, Gunhild; Knudsen, Jes S.; Ravn-Petersen, Lise S.; Torssell, Kurt B. G.
Tetrahedron, 1983 , vol. 39, # 13 p. 2237 - 2240
参考文献
Bestmann, Hans Juergen; Schade, Gerold; Luetke, Harry; Moenius, Thomas
Chemische Berichte, 1985 , vol. 118, # 7 p. 2640 - 2658
反应条件
sodium hydride in benzene
Heating;
参考文献
Haelters, J. P.; Corbel, B.; Sturtz, G.
Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 53 - 74
反应条件
chromium(VI) oxide; acetic acid
T=30°C;
参考文献
Fieser; Szmuszkovicz
Journal of the American Chemical Society, 1948 , vol. 70, p. 3352,3354
反应条件
oxygen; [Bu4N]4W10O32 in acetonitrile
T=5 - 10°C; 0.25 h; Irradiation; Further byproducts given. Title compound not separated from byproducts;
参考文献
Lykakis, Ioannis N.; Orfanopoulos, Michael
Synlett, 2004 , # 12 p. 2131 - 2134
反应条件
(i) NaOEt, EtOH, (ii) /BRN= 606474/, (iii) aq. NaOH; Multistep reaction;
参考文献
Riemschneider,R.; Nerin,R.
Monatshefte fuer Chemie, 1960 , vol. 91, p. 829 - 835
反应条件
1.1: iPrMgCl; Ti(OiPr)4 / diethyl ether / -78 - -20 °C
1.2: diethyl ether / -20 - 20 °C
2.1: H2O
View Scheme
参考文献
Laroche, Christophe; Bertus, Philippe; Szymoniak, Jan
Chemical Communications, 2005 , # 24 p. 3030 - 3032
