5-亚甲基螺[2.4]庚烷合成路线 （共 27 条）
反应条件
monoethoxy-diethylaluminum; tri-iso-propyl phosphine; palladium(II) 2,4-pentanedionate in benzene
T=115°C; P=463370 Torr; 6 h; further catalyst: Pd(PhCH=CH-CO-CH=CHPh)2;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1980 , vol. 113, # 10 p. 3334 - 3341
反应条件
trans-cinnamic acid methyl ester; tri-iso-propyl phosphine; (η3-allyl)(η5-Cp)Pd in toluene
T=120°C; 10 h; Yields of byproduct given;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1981 , vol. 114, # 10 p. 3313 - 3324
反应条件
tri-iso-propyl phosphine; bis(dibenzylideneacetone)-palladium(0) in benzene
T=115°C; 16 h; further catalyst: Pd-acetylacetonate, Pd(PPh3)4; variation of conc., temp.; Product distribution;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1980 , vol. 113, # 10 p. 3334 - 3341
反应条件
methylene cyclopropane; palladium(II) 2,4-pentanedionate; monoethoxy-diethylaluminum; tri-iso-propyl phosphine in benzene
T=100°C; P=3040 Torr; 2 h;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1980 , vol. 113, # 3 p. 1063 - 1071
反应条件
triphenylphosphine; (η3-allyl)(η5-Cp)Pd in toluene
T=136°C; P=22501.8 Torr; 18 h; Further byproducts given;
参考文献
Binger, Paul; Weintz, Hans-Joachim
Chemische Berichte, 1984 , vol. 117, # 2 p. 654 - 665
反应条件
monoethoxy-diethylaluminum; tri-iso-propyl phosphine; bis(acetylacetonato) palladium in toluene
T=100°C; 16 h; Title compound not separated from byproducts;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1981 , vol. 114, # 10 p. 3313 - 3324
反应条件
tri-iso-propyl phosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=100°C; 16 h; Yield given;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1981 , vol. 114, # 10 p. 3313 - 3324
反应条件
methylene cyclopropane; bis(dibenzylideneacetone)-palladium(0); tri-iso-propyl phosphine in benzene
T=100°C; 3 h; Further byproducts given;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1980 , vol. 113, # 3 p. 1063 - 1071
反应条件
tri-iso-propyl phosphine; (η3-allyl)(η5-Cp)Pd in toluene
T=110°C; 8 h;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1981 , vol. 114, # 10 p. 3313 - 3324
反应条件
tri-iso-propyl phosphine; bis(dibenzylideneacetone)-palladium(0) in benzene
T=100°C; 4 h; further catalyst: Pd acetylacetonate;
参考文献
Binger, Paul; Schuchardt, Ulf
Chemische Berichte, 1980 , vol. 113, # 10 p. 3334 - 3341
