1,2,3,4,5,5,6,6-八氟-1,3-环己二烯合成路线 (共 10 条)
反应条件
vanadium(V) fluoride in monofluoro-trichloromethane T=-25°C; 0.25 h;
参考文献
Bardin, V. V.; Avramenko, A. A.; Furin, G. G.; Krasilnikov, V. A.; Karelin, A. I.; et al.
Journal of Fluorine Chemistry, 1990 , vol. 49, # 3 p. 385 - 400
反应条件
1: 4-isopropenyl-1-methyl-cyclohexene / 180 °C 2: 600 °C View Scheme
参考文献
Anderson,L.P. et al.
Journal of the Chemical Society [Section] C: Organic, 1969 , p. 211 - 217
反应条件
sodium tetrahydroborate in diethylene glycol dimethyl ether T=-5°C; 1.25 h;
参考文献
Journal of Fluorine Chemistry, , vol. 24, p. 41 - 60
反应条件
sodium tetrahydroborate in diethylene glycol dimethyl ether T=-5°C; 0.25 h;
参考文献
Dodsworth, D. J.; Jenkins, C. M.; Stephens, R.; Tatlow, J. C.
Journal of Fluorine Chemistry, 1984 , vol. 24, p. 41 - 60
反应条件
nickel T=630 - 660°C;
参考文献
Gething et al.
Nature (London, United Kingdom), 1959 , vol. 183, p. 588
反应条件
sodium tetrahydroborate in diethylene glycol dimethyl ether T=-5°C; 1.25 h;
参考文献
Dodsworth, D. J.; Jenkins, C. M.; Stephens, R.; Tatlow, J. C.
Journal of Fluorine Chemistry, 1984 , vol. 24, p. 41 - 60
反应条件
sodium tetrahydroborate in diethylene glycol dimethyl ether T=-5°C; 0.25 h;
参考文献
Dodsworth, D. J.; Jenkins, C. M.; Stephens, R.; Tatlow, J. C.
Journal of Fluorine Chemistry, 1984 , vol. 24, p. 41 - 60
反应条件
T=38°C; P=55 Torr; 3 h;
参考文献
Hrabal, R.; Chvatal, Z.; Dedek, V.
Journal of Fluorine Chemistry, 1993 , vol. 63, # 3 p. 185 - 192
反应条件
quartz in gaseous matrix
T=475°C; effect of aging; catalytic behavior of fluoride ion; other reagent (NaF); using Pyrex glass instead of quartz; Product distributionMechanism;
参考文献
Burdon, J.; Childs, A.; Parsons, I. W.; Rimmington, T. W.
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 75 - 86
反应条件
1: KOH
2: aq. ethanol / (electrochemical reduction)
View Scheme
参考文献
Doyle,A.M.; Pedler,A.E.
Journal of the Chemical Society [Section] C: Organic, 1971 , p. 282 - 288