1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere; Cooling with acetone-dry ice 1.2: -78 - 4 °C / Inert atmosphere 2.1: tris-(dibenzylideneacetone)dipalladium(0); [(R)-methoxy(furyl)BIPHEP]; cesium fluoride / tetrahydrofuran; water / 12 h / 80 °C / Inert atmosphere View Scheme

1.1: tetrahydrofuran / 2 h / 0 °C / Inert atmosphere 2.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere; Cooling with acetone-dry ice 2.2: -78 - 4 °C / Inert atmosphere 3.1: tris-(dibenzylideneacetone)dipalladium(0); [(R)-methoxy(furyl)BIPHEP]; cesium fluoride / tetrahydrofuran; water / 12 h / 80 °C / Inert atmosphere View Scheme

暂无反应条件数据

bei 144grad erfolgt Dissoziation;

1: benzene; methanol. KOH; sulfur / weiteres Edukt: Diazomethan; Reaktion ueber mehrere Stufen 2: KMnO4 3: acetic acid anhydride View Scheme