二氯苯基钌(II)二聚体合成路线 （共 11 条）
反应条件
in ethanol; water RuCl3*nH2O was dissolved in 90 percent EtOH followed by dropwise addn. 1,3-cyclohexadiene, heated to reflux (85°C) for 4 h; ppt. was filtered off, washed with EtOH and dried in vacuo;
参考文献
Inorganic Chemistry, , vol. 50, # 19 p. 9714 - 9727
反应条件
HCl in nitromethane complex dissolved in CH3NO2, anhyd. HCl gas passed through the stirred soln. for 20 min; filtered off, soln. evapd., dissolved in MeOH, pptd. with NaBPh4, filtered off, washed with MeOH, air dried;
参考文献
Journal of Organometallic Chemistry, , vol. 263, # 3 p. 375 - 384
反应条件
in ethanol treating soln. of RuCl3 (0.0065 mol) in 90percent alc. with 1.3-cyclohexadiene (0.0065 mol), stirring mixt. for 3 h at 45°C; pptn., filtering after 12 h, washing with alc. and ether, drying in vac.; elem. anal.;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, p. 1922 - 1926
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 2071 - 2076
反应条件
HCl in methanol; nitromethane Ru complex dissolved in MeNO2, HCl gas passed through soln. for 20 min, (i), remaining soln. evapd., dissolved in MeOH, NaBPh4 added, (ii); (i) solid filtered off, washed with Et2O, air-dried; (ii) ppt. filtered off, washed with MeOH, air-dried;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 3 p. 365 - 378
反应条件
in ethylene glycol under N2; mixt. of RuCl3*3H2O and MeOC6H7 (excess) in HOCH2CH2OH heated to 80°C for 3 h; stored at room temp. overnight; filtered; ppt. washed with MeOH, dried in vac.; additional portion of Rucomplex obtained by evaporating under reduced pressure the filtrate to third of vol.; elem. anal.;
参考文献
Organometallics, , vol. 24, # 10 p. 2538 - 2541
反应条件
in ethanol mixt. of Ru compd. and diene (11 equiv.) in ethanol was refluxed for 12 h; cooled; filtered under suction; washed (methanol);
参考文献
Journal of the Chemical Society. Perkin Transactions 1, , # 3 p. 416 - 427
反应条件
in ethanol under N2; soln. of RuCl3*3H2O and MeOC6H7 (excess) in EtOH heated under reflux for 8 h; stored at room temp. overnight; filtered; ppt. extd. with CHCl3 (Soxlet extractor), solvent removed in vac., washed with Et2O; additional portion of Ru complex obtained by reducing the vol. of filtrate to half and refrigerating overnight; elem. anal.;
参考文献
Organometallics, , vol. 24, # 10 p. 2538 - 2541
反应条件
hydrogenchloride in acetone byproducts: 1,5-cyclooctadiene; (N2); addn. of a soln. of 36percent aq. HCl in acetone to a soln. of Ru(η6-benzene)(η4-COD) in acetone;; concg. the soln. to 3 ml and keeping it at -20 °C;;
参考文献
Journal of Organometallic Chemistry, , vol. 354, p. 117 - 122
反应条件
in ethanol; water Ru salt refluxed in degassed aq. EtOH with excess of diene under N2 for5-10 min;
参考文献
Journal of Organometallic Chemistry, , vol. 208, # 3 p. 369 - 387
反应条件
in ethanol; water according to R.A. Zelonka, M.C. Baird, Can. J. Chem. 50 (1972) 3063-3072, under N2, EtOH aq. 90percent, 45°C, 3 h;
参考文献
Journal of Organometallic Chemistry, , vol. 714, p. 88 - 93
