6,13-双(三异丙基甲硅烷基乙炔基)并五苯合成路线 （共 3 条）
反应条件
1: (Tri-iso-propylsilyl)acetylene With n-butyllithium in tetrahydrofuran T=20°C; 0.666667 h; Inert atmosphere; 2: 6,13-pentacenequinone in tetrahydrofuran Inert atmosphere; 3: With hydrogenchloride; SnCl2 in tetrahydrofuran; water 7 h; Inert atmosphere;
参考文献
Chen, Jihua; Subramanian, Sankar; Parkin, Sean R.; Siegler, Maxime; Gallup, Kaitlin; Haughn, Chelsea; Martin, David C.; Anthony, John E.
Journal of Materials Chemistry, 2008 , vol. 18, # 17 p. 1961 - 1969
反应条件
1: in tetrahydrofuran T=60°C; Grignard reaction; 2: With tin(ll) chloride in tetrahydrofuran T=60°C; Further stages.;
参考文献
Anthony, John E.; Eaton, David L.; Parkin, Sean R.
Organic Letters, 2002 , vol. 4, # 1 p. 15 - 18
反应条件
1.1: n-butyllithium / hexane / 0.67 h / 0 °C / Inert atmosphere 1.2: 0 - 20 °C / Inert atmosphere 2.1: SnCl2·2H2O; sulfuric acid / water; acetone View Scheme
参考文献
Djukic, Brandon; Perepichka, Dmitrii F.
Chemical Communications, 2012 , vol. 48, # 53 p. 6651 - 6653
