1.1: Grubb's 2nd generation catalyst / 6 h / 30 °C / 760.05 Torr
2.1: sulfuric acid / water / 6 h / Heating; Reflux; Industry scale
3.1: ozone; oxygen; acetic acid / 7 h / Cooling with water bath; Industry scale
3.2: Industry scale
View Scheme
1: oleic acid; 18:2 ω-6; palmitoleic acid; ethyl stearic acid; hexadecanoic acid; octadecanoic acid With Grubbs II
T=50 - 53°C; 20 - 72 h; Neat (no solvent);
2: With ethyl vinyl ether
3: methanol With sulfuric acid
Product distribution / selectivity;
参考文献
The United States of America as represented by the Secretary of Agriculture
Patent: US7534917 B1, 2009 ;
Location in patent: Page/Page column 12-13; 18 ;
1: oleic acid; 18:2 ω-6; palmitoleic acid; ethyl stearic acid; hexadecanoic acid; octadecanoic acid; 18:3 ω-3 With Grubbs II
T=50 - 75°C; 8 - 72 h; Neat (no solvent);
2: With ethyl vinyl ether
3: methanol With sulfuric acid
1 h; Heating / reflux; Product distribution / selectivity;
参考文献
The United States of America as represented by the Secretary of Agriculture
Patent: US7534917 B1, 2009 ;
Location in patent: Page/Page column Sheet 5/6; 11; 12; 14; 18 ;
