反应条件
1: 84 percent / Li2CuCl4 / tetrahydrofuran; diethyl ether / 3 h / 0 °C
2: 1.) 0.75M 9-borabicyclo<3.3.1>nonane; 2.) 3N NaOH, 26percent H2O2 / 1.) THF, 0 deg C, 2-3 h; 2.) 20 deg C, 2-3 h
3: PBr3 / 1.) pyridine, hexane, 3-5 deg C, 3h; 2.) 20 deg C, 12 h
4: 1.) Mg / 1.) ether; 2.) ether; HCl
5: 90 percent / LiAlH4 / diethyl ether
View Scheme
参考文献
Zakharkin, L. I.; Petrushkina, E. A.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1419 - 1422
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1623 - 1628
