1,4-双(二氟甲基)苯合成路线 （共 20 条）
反应条件
pyridine hydrogenfluoride; 1,3-dibromo-5,5-dimethyl-hydantoin in dichloromethane As in EXAMPLE 1;
参考文献
Nippon Shokubai Co., Ltd.
Patent: US6384289 B1, 2002 ;
Location in patent: Page column 10 ;
反应条件
1: 80 percent / Br2 / 5 h / 130 - 160 °C 2: 85 percent / SbF3 / 120 °C / 40 Torr View Scheme
参考文献
Grechkina, E. V.; Sochilin, V. A.; Pebalk, A. V.; Kardash, I. E.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 10 p. 1663 - 1665
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 10 p. 1999 - 2001
参考文献
Nippon Shokubai Co., Ltd.
Patent: US6384289 B1, 2002 ;
Location in patent: Claim ;
参考文献
Nippon Shokubai Co., Ltd.
Patent: US6384289 B1, 2002 ;
Location in patent: Page column 10 ;
反应条件
1: 55 percent / N-bromosuccinimide / CCl4 / Heating; Irradiation 2: Cu / 640 °C 3: toluene / 110 °C View Scheme
参考文献
Chow,S.W. et al.
Journal of Organic Chemistry, 1970 , vol. 35, p. 20 - 22
反应条件
N-bromosuccinmide in tetrachloromethane HeatingIrradiation;
参考文献
Dolbier, William R.; Asghar, Mohammed Ali; Pan, He-Qi; Celewicz, Lech
Journal of Organic Chemistry, 1993 , vol. 58, # 7 p. 1827 - 1830
反应条件
chlorine T=60°C; P=760.051 Torr; 1.66667 h; Irradiation; TimeTemperatureReagent/catalyst;
参考文献
Chung-shan Institute of Science and Technology. Armaments Bureau. M.N.D.; Yuan-Shin Materials Technology Corp.; LIN, Chun-Hsu; Yin, Hung-Cheng; Sun, Chien-Yi; Yin, Yung-Yu; Chou, Chuan-Yu
Patent: US2013/116482 A1, 2013 ;
Location in patent: Paragraph 0036; 0037; 0038 ;
反应条件
chlorine in tetrachloromethane
参考文献
Union Carbide Chemicals and Plastics Technology Corporation
Patent: US5210341 A1, 1993 ;
反应条件
bromine in tetrachloromethane HeatingIrradiation;
参考文献
Fuqua,S.A. et al.
Tetrahedron, 1964 , vol. 20, p. 1625 - 1632
反应条件
triethylsilane; C24BF20(1-)*C18F16P(1+) T=20°C; 24 h;
参考文献
Caputo, Christopher B.; Hounjet, Lindsay J.; Dobrovetsky, Roman; Stephan, Douglas W.
Science, 2013 , vol. 341, # 6152 p. 1374 - 1377
