1,1,2,2-四甲基-二膦合成路线 （共 33 条）
反应条件
sodium amide 1.) NH3(liq.), -78 deg C, 30 min, 2.) NH3(liq.), -78 deg C, 1 h; Multistep reaction;
参考文献
Kita, Masakazu; Yamamoto, Takashi; Kashiwabara, Kazuo; Fujita, Junnosuke
Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 8 p. 2272 - 2274
参考文献
Dehnert,P. et al.
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1979 , vol. 34, p. 1646 - 1652
反应条件
chloro-diphenylphosphine 2 h;
参考文献
Wolfsberger, W
Journal of Organometallic Chemistry, 1986 , vol. 317, p. 167 - 174
参考文献
Noeth,H.
Z. Naturforsch., B: Anorg. Chem., Org. Chem., Biochem., Biophys.,, 1960 , vol. 15, p. 327 - 329
反应条件
ammonia; sodium T=-78°C; 1) 1 h 2) 30 min 3) 1 h;
参考文献
Kita, Masakazu; Okuyama, Akiyoshi; Kashiwabara, Kazuo; Fujita, Junnosuke
Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 7 p. 1994 - 2001
参考文献
Dehnert,P. et al.
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1979 , vol. 34, p. 1646 - 1652
反应条件
1.) K 1.) THF, 30-40 deg C, 1 d, 2.) THF, a) RT, overnight, b) reflux, 2 h; Yield given. Multistep reaction;
参考文献
Suzuki, Takayoshi; Kashiwabara, Kazuo; Fujita, Junnosuke
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 6 p. 1619 - 1626
参考文献
Cooper,P. et al.
Journal of the Chemical Society [Section] C: Organic, 1971 , p. 3031 - 3035
反应条件
tributylphosphine
T=170°C; 1 h;
参考文献
Pindzola, Brad A.; Jin, Jizhu; Gin, Douglas L.
Journal of the American Chemical Society, 2003 , vol. 125, # 10 p. 2940 - 2949
反应条件
phosphorus; sodium hydroxide; tri-n-butylhexadecylphosphonium bromide in water; toluene
T=-10 - 60°C; 4 h;
参考文献
Clariant GmbH
Patent: US6806383 B1, 2004 ;
Location in patent: Page column 3-4 ;
