3-甲基-5-苯基-2-戊醇合成路线 （共 7 条）
反应条件
bis(cyclopentadienyl)titanium dichloride; manganese; Wilkinson's catalyst; hydrogen; 4-chloro-2,6-dimethylpyridine hydrochloride in tetrahydrofuran
T=25°C; P=3000.3 Torr; 20 h; Inert atmosphere;
参考文献
Gansaeuer, Andreas; Otte, Matthias; Piestert, Frederik; Fan, Chun-An
Tetrahedron, 2009 , vol. 65, # 26 p. 4984 - 4991
反应条件
10 Pd(OH)2/C; hydrogen; caesium carbonate in acetonitrile
T=0°C; P=750.075 Torr; 1 h; optical yield given as percent de;
参考文献
Fordred, Paul S.; Niyadurupola, D.Gangani; Wisedale, Richard; Bull, Stevend
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 14-15 p. 2310 - 2314
反应条件
1: 96.4 percent / acetyl chloride
2: benzene; diethyl ether / 3 h / Heating
View Scheme
参考文献
Morin,F.G.; Horton,W.J.; Grant,D.M.
Journal of the American Chemical Society, 1983 , vol. 105, p. 3992
反应条件
1: 75.9 percent / H2
2: 96.4 percent / acetyl chloride
3: benzene; diethyl ether / 3 h / Heating
View Scheme
参考文献
Morin,F.G.; Horton,W.J.; Grant,D.M.
Journal of the American Chemical Society, 1983 , vol. 105, p. 3992
反应条件
in diethyl ether; benzene
3 h; Heating;
参考文献
Morin,F.G.; Horton,W.J.; Grant,D.M.
Journal of the American Chemical Society, 1983 , vol. 105, p. 3992
反应条件
1: benzene
2: NaBH4
View Scheme
参考文献
Khalaf,A.A.; Roberts,R.M.
Journal of Organic Chemistry, 1972 , vol. 37, # 26 p. 4227 - 4235
反应条件
sodium tetrahydroborate
参考文献
Khalaf,A.A.; Roberts,R.M.
Journal of Organic Chemistry, 1972 , vol. 37, # 26 p. 4227 - 4235
