3-甲氧基-3-甲基丁烷-2-酮合成路线 （共 14 条）
反应条件
sulfuric acid; magnesium sulfate in methanol; water
参考文献
The Dow Chemical Company
Patent: US4215127 A1, 1980 ;
反应条件
sulfuric acid; mercury(II) oxide in tetrahydrofuran
参考文献
Kagan,J.; Przybytek,J.T.
Tetrahedron, 1973 , vol. 29, p. 1163 - 1167
反应条件
1: 52 percent / triethylamine / dimethylformamide / 18 h / 85 - 90 °C
2: 94 percent Chromat. / silver perchlorate, triethylamine / tetrahydrofuran; diethyl ether / 0.25 h / -30 °C
3: methanol
View Scheme
参考文献
Shimizu, Nobujiro; Tanaka, Masayuki; Tsumo, Yuho
Journal of the American Chemical Society, 1982 , vol. 104, # 5 p. 1330 - 1340
反应条件
methanol
Yield given;
参考文献
Shimizu, Nobujiro; Tanaka, Masayuki; Tsumo, Yuho
Journal of the American Chemical Society, 1982 , vol. 104, # 5 p. 1330 - 1340
反应条件
zinc cyanide in methanol
20 h; Heating;
参考文献
De Kimpe, Norbert; Sulmon, Paul; Verhe, Roland; De Buyck, Laurent; Schamp, Niceas
Journal of Organic Chemistry, 1983 , vol. 48, # 23 p. 4320 - 4326
反应条件
potassium hydrogensulfate
T=100°C; Destillation; zuletzt bei 180grad;
参考文献
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 219
Chem.Abstr., 1942 , p. 746
反应条件
sodium hydroxide
T=60°C;
参考文献
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 219
Chem.Abstr., 1942 , p. 746
反应条件
potassium hydroxide
T=50 - 90°C;
参考文献
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 219
Chem.Abstr., 1942 , p. 746
反应条件
1: methanol; HgO; BF3-etherate / 45 - 55 °C / Reagens 4: Trichloressigsaeure
2: diluted HCl
3: aq. NaOH solution / 60 °C
View Scheme
参考文献
Nasarow
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1940 , p. 219
Chem.Abstr., 1942 , p. 746
反应条件
1: aq. KOH
2: aq. H2SO4, HgO
View Scheme
参考文献
Hennion,G.F.; Boisselle,A.P.
Journal of Organic Chemistry, 1961 , vol. 26, p. 2677 - 2681
