双(2-乙基己基)亚磷酸酯合成路线 (共 9 条)
反应条件
phosphorus trichoride in benzene T=20°C; Condensation; 2 h;
参考文献
Deng, Chang-Hui; Li, Yan-Mei; Xu, Ning; Zhao, Yu-Fen
Journal of Chemical Research, Miniprint, 1999 , # 10 p. 2552 - 2560
反应条件
1: mono-2-ethyl-1-hexyl phosphite With phosphorous pentoxide T=54°C; 3 h; Inert atmosphere; 2: 2-ethyl-n-hexanol T=56°C; 0.5 h; Inert atmosphere;
参考文献
Straitmark Holding AG; Cogels, Samuel Corentin; Notté, Patrick
Patent: EP2581378 A1, 2013 ;
Location in patent: Paragraph 0038; 0039; 0043 ;
参考文献
Journal of the American Chemical Society, , vol. 74, p. 1528,1530
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), , vol. 36, p. 1853,1857; engl. Ausg. S. 1792, 1795
参考文献
Journal of the American Chemical Society, , vol. 74, p. 1528,1530
Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), , vol. 36, p. 1853,1857; engl. Ausg. S. 1792, 1795
参考文献
Grosse-Ruyken; Uhlig
Journal fuer Praktische Chemie (Leipzig), 1962 , vol. <4>18, p. 287,289
反应条件
potassium hydroxide; potassium carbonate in benzene
6 h; Ambient temperatureother diarylphosphine oxides and dialkyl hydrogen phosphites, var. alkylating agents, var. reaction times, also in the presence 18-crown-6, and phase transfer catalysis; Product distribution;
参考文献
Petrov, K. A.; Sivova, L. I.; Smirnov, I. V.; Kryukova, L. Yu.
J. Gen. Chem. USSR (Engl. Transl.), 1992 , vol. 62, # 2.1 p. 327 - 332,264 - 268
反应条件
sodium hydroxide; Aliquatreg; 336 in dichloromethane
T=20 - 25°C; 4 h; Yield given;
参考文献
Kem, Kenneth M.; Nguyen, Nghi V.; Cross, Dennis J.
Journal of Organic Chemistry, 1981 , vol. 46, p. 5188 - 5192
反应条件
sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride in dichloromethane
T=0 - 5°C; 3.33333 h;
参考文献
Ye, Wezhen; Liao, Xiugao
Synthesis, 1985 , # 10 p. 986 - 988
反应条件
sodium in diethyl ether; benzene
Michaelis-Becker reaction; Heating;
参考文献
Cherkasov; Garifzyanov; Krasnova; Talan
Russian Journal of General Chemistry, 2006 , vol. 76, # 10 p. 1537 - 1544