tetrakis(triphenylphosphine) palladium(0); cesium fluoride in tetrahydrofuran Suzuki coupling; 48 h; RefluxInert atmosphere;

tetrakis(triphenylphosphine) palladium(0); cesium fluoride in tetrahydrofuran Suzuki coupling; 48 h; RefluxInert atmosphere;

tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol; water; toluene Suzuki coupling; 48 h; RefluxInert atmosphere;

tetrakis(triphenylphosphine) palladium(0); potassium carbonate in water; toluene T=110°C; Suzuki Coupling; 12 h;

1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; water / 12 h / 110 °C 2: N-bromosuccinmide / chloroform / 24 h / 20 °C / |Darkness View Scheme

potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in 1,4-dioxane T=80°C; Inert atmosphere;

1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With 4,4'-dimethyl-2,2'-bipyridine; bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); potassium tert-butylate in tetrahydrofuran T=50°C; 0.166667 h; Inert atmosphere; 2: benzene in tetrahydrofuran T=85°C; 96 h; Inert atmosphere;

Cp*Rh(η4-C6Me6) in cyclohexane T=150°C; 61 h; Title compound not separated from byproducts.;

CoCp(C2H4)2 in tetrahydrofuran T=20°C; 1 h; Title compound not separated from byproducts.;

1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With 4,4'-dimethyl-2,2'-bipyridine; bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); potassium tert-butylate in tetrahydrofuran T=50°C; 0.25 h; Inert atmosphere; 2: 1,4-benzenediboronic acid bis(pinacol)ester in tetrahydrofuran T=85°C; 96 h; Inert atmosphere;