tetrabutyl ammonium fluoride in tetrahydrofuran; 1,4-dioxane T=20°C; 0.166667 h;

citrate buffer; N-deoxyribosyltransferase from L. leichmannii in ethanol T=40°C; 48 h;

nickel

1: 81 percent / dimethylformamide; pyridine / 1 h / 20 °C 2: 86 percent / DMAP / acetonitrile / 2 h / 20 °C 3: 66 percent / Bu3SnH, AIBN / benzene / 5 h / 80 °C 4: 91 percent / tetrabutylammonium fluoride / tetrahydrofuran; dioxane / 0.17 h / 20 °C View Scheme

1: 86 percent / DMAP / acetonitrile / 2 h / 20 °C 2: 66 percent / Bu3SnH, AIBN / benzene / 5 h / 80 °C 3: 91 percent / tetrabutylammonium fluoride / tetrahydrofuran; dioxane / 0.17 h / 20 °C View Scheme

1: 66 percent / Bu3SnH, AIBN / benzene / 5 h / 80 °C 2: 91 percent / tetrabutylammonium fluoride / tetrahydrofuran; dioxane / 0.17 h / 20 °C View Scheme

sodium cacodylate buffer; water T=110°C; 22 h; ΔH(excit.); var. temp. and times; KineticsThermodynamic dataMechanism;