2,4,6-三甲基苯磺酰羟胺合成路线 （共 27 条）
反应条件
perchloric acid in 1,4-dioxane; water T=0°C; 0.116667 h;
参考文献
ISIS INNOVATION LIMITED
Patent: US2012/178913 A1, 2012 ;
Location in patent: Page/Page column 8-9 ;
反应条件
1: With triethylamine T=20°C; 2: With perchloric acid Neat (no solvent);
参考文献
MERCK and CO., INC.; KATZ, Jason; KNOWLES, Sandra, L.; JEWELL, James, P.; SLOMAN, David, L.; STANTON, Matthew, G.; NOUCTI, Njamkou
Patent: WO2010/17046 A1, 2010 ;
Location in patent: Page/Page column 42; 57-58 ;
WO 2010/017046 A1
反应条件
trifluoroacetic acid in tetrahydrofuran T=0°C; 0.5 h; Inert atmosphere; Concentration;
参考文献
MERCK PATENT GMBH; SCHIEMANN, Kai; DEUTSCH, Carl; HOELZEMANN, Guenter; KUHN, Daniel; WEGENER, Ansgar; SWINNEN, Dominique; COMAS, Horacio
Patent: WO2013/131609 A1, 2013 ;
Location in patent: Page/Page column 96 ;
反应条件
perchloric acid in 1,4-dioxane ice-cooling;
参考文献
Organic and Biomolecular Chemistry, , vol. 6, # 1 p. 175 - 186
反应条件
hydrogenchloride in diethyl ether
参考文献
Sumitomo Chemical Company, Limited
Patent: US2002/19569 A1, 2002 ;
反应条件
hydrogenchloride in methanol
参考文献
Synthesis, , p. 788 - 789
反应条件
in diethyl ether To (C5Cl4Br)Mn(CO)3 in Et2O is added first BuLi at -60°C and then is added MesSO2ON(SiMe3)2 under N2, reaction mixture is warmed up to room temp.; evapn. of Et2O under vac., residue is stirred with hexane, hexane soluble part is washed (H2O), dried over MgSO4, and filtered, addn. of Et2O, H2O and HCl, sepn. of the orange ether phase and drying, filtn., after addn. of hexane ppt. is obtained;
参考文献
Suenkel, Karlheinz; Steiner, Doris
Journal of Organometallic Chemistry, 1989 , vol. 368, p. 67 - 76
反应条件
in dichloromethane T=0 - 20°C; 4 h;
参考文献
Borodkin; Vorob'ev; Shakirov; Shubin
Russian Journal of Organic Chemistry, 2011 , vol. 47, # 6 p. 889 - 896
反应条件
in tetrahydrofuran; water; mineral oil
参考文献
BASF Aktiengesellschaft
Patent: US6376426 B1, 2002 ;
