in diethyl ether (glovebox or high vac.); Et2O vac. transferred to LiN(CH3)2, cooled to 0°C, suspn. of Mo-complex in Et2O added, stirred for 4 h, stirred at 23°C for 48 h; Et2O removed in vacuo, cooled with dry ice/acetone mixt., residue heatedto 80°C for 2 h at 1E-3 Torr, collected;
参考文献
Kuiper, David S.; Wolczanski, Peter T.; Lobkovsky, Emil B.; Cundari, Thomas R.
Inorganic Chemistry, 2008 , vol. 47, # 22 p. 10542 - 10553
in hexane under N2, slow addn. (with stirring) of a hexane slurry of LiNMe2 to a cooled (ice bath) hexane soln. of AlCl3, reaction mixture was allowed to warm up to room temp., stirred for 10 h; filtration, concn. under reduced pressure, crystn. at -20°C;
参考文献
Waggoner, K. M.; Olmstead, M. M.; Power, P. P.
Polyhedron, 1990 , vol. 9, p. 257 - 264
1: in tetrahydrofuran; hexane T=10°C; 2: With sodium hydrogencarbonate; sodium carbonate in tetrahydrofuran; hexane; water T=5 - 20°C; 12 h; Product distribution / selectivity;
