1,1-二(4-氟苯基)-2-1-丙醇合成路线 （共 14 条）
反应条件
1: 100 percent / sulfuric acid / H2O; dioxane / 0.08 h / Heating
2: 31 percent / Ti(OEt)4 / toluene / 3 h / 110 °C
View Scheme
参考文献
Teral, Yannick; Roubaud, Gabriel; Aubert, Claude; Faure, Robert; Campredon, Mylene
Australian Journal of Chemistry, 2005 , vol. 58, # 7 p. 517 - 521
反应条件
1: 61 percent / PPh3; H2 / HRh(CO)(PPh3)3 / toluene / 24 h / 100 °C / 76000 Torr
2: 90 percent / NaBH4; aq. NaOH / methanol / 3 h / 20 °C
3: 85 percent / H2 / 10 percent Pd/C / aq. ethanol / Heating
View Scheme
参考文献
Botteghi, Carlo; Marchetti, Mauro; Paganelli, Stefano; Persi-Paoli, Francesco
Tetrahedron, 2001 , vol. 57, # 8 p. 1631 - 1637
反应条件
1: 61 percent / PPh3; H2 / HRh(CO)(PPh3)3 / toluene / 24 h / 100 °C / 76000 Torr
2: 90 percent / NaBH4; aq. NaOH / methanol / 3 h / 20 °C
3: 85 percent / H2 / 10 percent Pd/C / aq. ethanol / Heating
4: 80 percent / Br2; PPh3 / acetonitrile / 2 h / 20 °C
View Scheme
参考文献
Botteghi, Carlo; Marchetti, Mauro; Paganelli, Stefano; Persi-Paoli, Francesco
Tetrahedron, 2001 , vol. 57, # 8 p. 1631 - 1637
反应条件
trans-[RuCl2(η3:η3-2,7-dimethylocta-2,6-diene-1,8-diyl)(PPh3)] in water
T=60°C; 24 h; Sealed tubeInert atmosphere;
参考文献
Cadierno, Victorio; Francos, Javier; Gimeno, Jose
Organometallics, 2011 , vol. 30, # 4 p. 852 - 862
