potassium thioacyanate in water byproducts: ethyl 3,5-dimethylpyrrole-2-carboxylate; addn. soln. od KCN to soln. of Tl compound, stirring (room temp., 30 min); filtration off thallium(I) thiocyanate, extn. filtrate (CH2Cl2), washing precipitate (CH2Cl2), drying (Na2SO4, vac.), chromy. (silica gel, hexane/AcOEt=3/1); m. p. and IR for thiocyanopyrrole derivative;

暂无反应条件数据

sulfur in water boiling an aq. soln. of TlCN with S;;

in not given dild. TlNO3 soln. pptd. with dild. NH4CNS soln.;;

in not given pptn.;; washed and recrystd. from hot H2O;;

in not given pptn.;;

in not given boiling a TlCN soln. with S;; crystn. after removal of S and Tl2S;;

in not given byproducts: HCN; passing H2S into a soln. of TlCN*Tl(CN)3 under warming;;

bromine in chloroform; water 0.5 h; Ambient temperature;

(i) I2, (ii) /BRN= 1071236/; Multistep reaction;