4-(三氟甲基硫代)甲苯合成路线 （共 35 条）
反应条件
1: para-thiocresol With sodium hydride in N,N-dimethyl-formamide T=20°C; Inert atmosphere; 2: perfluoromethyl iodide in N,N-dimethyl-formamide T=20°C; 14 h;
参考文献
Harsanyi, Antal; Dorko, Eva; Csapo, Agnes; Bako, Tibor; Peltz, Csaba; Rabai, Jozsef
Journal of Fluorine Chemistry, 2011 , vol. 132, # 12 p. 1241 - 1246
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide T=130°C; 24 h; Inert atmosphereSealed tubeGlovebox;
参考文献
Zhai, Lijuan; Li, Yaming; Yin, Jun; Jin, Kun; Zhang, Rong; Fu, Xinmei; Duan, Chunying
Tetrahedron, 2013 , vol. 69, # 48 p. 10262 - 10266
反应条件
copper in N,N,N',N',N'',N''-hexamethylphosphoric triamide 160 to 180°C, 12 h;
参考文献
Remy, D. C.; Rittle, K. E.; Hunt, C. A.; Freedman, M. B.
Journal of Organic Chemistry, 1976 , vol. 41, p. 1644 - 1646
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Gmelin Handbook: F: PerFHalOrg.SVol.2, 6.2.1.6.10, page 251 - 267
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Merck and Co., Inc.
Patent: US4020169 , 1977 ;
C.A., 1977 , vol. 87, p. 52939
反应条件
in N,N-dimethyl-formamide P=1520 Torr; Ambient temperature;
参考文献
Wakselman, Claude; Tordeux, Marc
Journal of Organic Chemistry, 1985 , vol. 50, # 21 p. 4047 - 4051
反应条件
in ammonia T=-70 - -30°C; 1 h; Irradiation;
参考文献
Ignat'ev, N. V.; Boiko, V. N.; Yagupol'skii, L. M.
Journal of Organic Chemistry USSR (English Translation), 1985 , vol. 21, # 3 p. 592
Zhurnal Organicheskoi Khimii, 1985 , vol. 21, # 3 p. 653
反应条件
lithium chloride in N,N-dimethyl-formamide electrolysis;
参考文献
Ignat'ev, N. V.; Datsenko, S. D.; Yagupol'skii, L. M.
Journal of Organic Chemistry USSR (English Translation), 1991 , vol. 27, # 5 p. 780 - 784
Zhurnal Organicheskoi Khimii, 1991 , vol. 27, # 5 p. 905 - 910
反应条件
CH3C6H4MgX in tetrahydrofuran byproducts: CH3C6H4Cl, CH3C6H4X, MgXCl;
参考文献
Gmelin Handbook: F: PerFHalOrg.1, 1.1.6.5.2, page 157 - 193
反应条件
in N,N-dimethyl-formamide
参考文献
Yagupol'skii, L. M.; Kondratenko, N. V.; Sanbur, V. P.
Synthesis, 1975 , p. 721 - 723
反应条件
in sulfolane T=230°C; 0.166667 h;
参考文献
Quiclet-Sire, Beatrice; Saicic, Radomir N.; Zard, Samir Z.
Tetrahedron Letters, 1996 , vol. 37, # 50 p. 9057 - 9058
反应条件
pyridine; sulfur dioxide; paraquat diiodide in acetonitrile perfluoroalkylation;
参考文献
Koshechko; Kiprianova; Fileleeva; Tsanov
Journal of Fluorine Chemistry, 1999 , vol. 96, # 2 p. 163 - 166
