(12Z)-12-十四碳烯-1-基乙酸酯合成路线 （共 11 条）
反应条件
nitric acid; sodium nitrite in water T=70 - 75°C; 1 h; Inert atmosphere;
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
反应条件
1: n-butyl-triphenylphosphonium bromide With potassium tert-butylate in tetrahydrofuran Inert atmosphere; 2: acetic acid 8-oxo-octyl ester in tetrahydrofuran T=-15 - 20°C; Inert atmosphere;
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
反应条件
1: 1.) I2, SnCl4 2.) Li2CuCl4 / 1.) CH2Cl2, 0 gradC, 1 h. 2.) THF 2: pyridine View Scheme
参考文献
Chan, T. H.; Koumaglo, K.
Tetrahedron Letters, 1986 , vol. 27, # 8 p. 883 - 886
反应条件
1.1: sulfuric acid / toluene / 15 h / 75 °C 2.1: pyridinium chlorochromate / dichloromethane / 20 °C 3.1: potassium tert-butylate / tetrahydrofuran / Inert atmosphere 3.2: -15 - 20 °C / Inert atmosphere 4.1: nitric acid; sodium nitrite / water / 1 h / 70 - 75 °C / Inert atmosphere View Scheme
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
反应条件
1.1: potassium tert-butylate / tetrahydrofuran / Inert atmosphere 1.2: -15 - 20 °C / Inert atmosphere 2.1: nitric acid; sodium nitrite / water / 1 h / 70 - 75 °C / Inert atmosphere View Scheme
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
反应条件
1.1: pyridinium chlorochromate / dichloromethane / 20 °C 2.1: potassium tert-butylate / tetrahydrofuran / Inert atmosphere 2.2: -15 - 20 °C / Inert atmosphere 3.1: nitric acid; sodium nitrite / water / 1 h / 70 - 75 °C / Inert atmosphere View Scheme
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
反应条件
1.1: sulfuric acid / toluene / 15 h / 75 °C 2.1: pyridinium chlorochromate / dichloromethane / 20 °C 3.1: potassium tert-butylate / tetrahydrofuran / Inert atmosphere 3.2: -15 - 20 °C / Inert atmosphere View Scheme
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
反应条件
1.1: pyridinium chlorochromate / dichloromethane / 20 °C 2.1: potassium tert-butylate / tetrahydrofuran / Inert atmosphere 2.2: -15 - 20 °C / Inert atmosphere View Scheme
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
参考文献
Chan, T. H.; Koumaglo, K.
Tetrahedron Letters, 1986 , vol. 27, # 8 p. 883 - 886
反应条件
nitric acid; sodium nitrite in water T=70 - 75°C; 1 h; Inert atmosphere;
参考文献
Li, Jiu-Ming; Yong, Jian-Ping; Huang, Feng-Lan; Bai, Shu-Zhen
Chemistry of Natural Compounds, 2012 , vol. 48, # 1 p. 103 - 105
