2-乙酰基-2-丙-2-烯基戊-4-烯酸乙酯合成路线 （共 25 条）
反应条件
potassium carbonate; [bmim]BF4 in N,N-dimethyl-formamide T=20°C; 2 h;
参考文献
Muthusamy, Sengodagounder; Gnanaprakasam, Boopathy
Tetrahedron Letters, 2005 , vol. 46, # 4 p. 635 - 638
反应条件
P(MeNCH2CH2)3N in hexane; acetonitrile T=0°C; 0.5 h;
参考文献
Arumugam, Subramaniam; McLeod, Dale; Verkade, John G.
Journal of Organic Chemistry, 1998 , vol. 63, # 11 p. 3677 - 3679
反应条件
tetrabutylammomium bromide; potassium carbonate; palladium dichloride in tetrahydrofuran Tsuji-Trost reaction; 7 h; Heating;
参考文献
Ranu, Brindaban C.; Chattopadhyay, Kalicharan; Adak, Laksmikanta
Organic Letters, 2007 , vol. 9, # 22 p. 4595 - 4598
反应条件
pyridine; magnesium sulfate; 1,2-(p-MeOC6H4)2cyclobuten[=P(2,4,6-tri-t-BuPh)]2PdOTf T=50°C; 3 h;
参考文献
Shibuya, Ryozo; Lin, Lu; Nakahara, Yasuhito; Mashima, Kazushi; Ohshima, Takashi
Angewandte Chemie - International Edition, 2014 , vol. 53, # 17 p. 4377 - 4381
Angew. Chem., 2014 , vol. 126, # 17 p. 4466 - 4470,5
反应条件
tetrabutylammomium bromide; potassium carbonate; palladium dichloride in tetrahydrofuran Tsuji-Trost reaction; 1.5 h; Heating;
参考文献
Ranu, Brindaban C.; Chattopadhyay, Kalicharan; Adak, Laksmikanta
Organic Letters, 2007 , vol. 9, # 22 p. 4595 - 4598
反应条件
tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate in tetrahydrofuran T=70°C; Tsuji-Trost Allylation; 18 h; Schlenk technique;
参考文献
Dickschat, Arne T.; Behrends, Frederik; Surmiak, Sabrina; Weiss, Mark; Eckert, Hellmut; Studer, Armido
Chemical Communications, 2013 , vol. 49, # 22 p. 2195 - 2197
反应条件
1: ethyl acetoacetate With sodium hydride in tetrahydrofuran T=25°C; 0.5 h; 2: ethylene,methyl acetate With bis(η3-allyl-μ-chloropalladium(II)); Tedicyp in tetrahydrofuran T=25°C; 20 h; Title compound not separated from byproducts;
参考文献
Ranu, Brindaban C.; Chattopadhyay, Kalicharan; Adak, Laksmikanta
Organic Letters, 2007 , vol. 9, # 22 p. 4595 - 4598
反应条件
potassium carbonate in tetrahydrofuran T=70°C; Tsuji-Trost Allylation; 18 h; Schlenk technique; Reagent/catalyst;
参考文献
Dickschat, Arne T.; Behrends, Frederik; Surmiak, Sabrina; Weiss, Mark; Eckert, Hellmut; Studer, Armido
Chemical Communications, 2013 , vol. 49, # 22 p. 2195 - 2197
反应条件
tetrakis(triphenylphosphine) palladium(0); triphenylphosphine in tetrahydrofuran 7 h;
参考文献
Lu, Xiyan; Jiang, Xiaohui; Tao, Xiaochun
Journal of Organometallic Chemistry, 1988 , vol. 344, p. 109 - 118
反应条件
1,2-bis-(diphenylphosphino)ethane; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in dichloromethane 48 h; Ambient temperature;
参考文献
Yamamoto, Yoshinori; Fujiwara, Naoya
Journal of the Chemical Society, Chemical Communications, 1995 , # 19 p. 2013 - 2014
