2,2′,4,4′,5,5′-六氯联苯合成路线 (共 15 条)
反应条件
1: bromobenzene With n-butyllithium in tetrahydrofuran; hexane 0.333333 h; cooling; 2: With zinc(II) chloride in tetrahydrofuran; hexane T=20°C; 0.333333 h; 3: 1,2,4,5-TeCB With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane Negishi coupling; 24 h; Heating;
参考文献
Russian Chemical Bulletin, , vol. 54, # 4 p. 970 - 974
反应条件
copper in N,N-dimethyl-formamide Ulman reaction; Heating;
参考文献
Chemosphere, , vol. 31, # 2 p. 2687 - 2705
反应条件
in isopropyl alcohol γ-Irradiation; Title compound not separated from byproducts;
参考文献
Chemosphere, , vol. 43, # 4-7 p. 485 - 491
反应条件
isopentyl nitrite T=130°C;
参考文献
Russian Journal of General Chemistry, , vol. 82, # 1 p. 138 - 143
反应条件
ammonium hydroxide; copper(l) chloride Diazotization;
参考文献
Zhurnal Obshchei Khimii, , vol. 29, p. 3428,3431; engl. Ausg. S. 3389, 3392
反应条件
(i) aq. HCl, (ii) NaNO2, (iii) CuCl, aq. HCl; Multistep reaction;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 686 - 691
反应条件
1: HNO3 2: Zn, aq. CuSO4 / acetic acid 3: (i) NaNO2, aq. H2SO4, (ii) CuCl, aq. HCl View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 686 - 691
反应条件
oxygen T=550 - 600°C; 0.00138889 h; Product distribution;
参考文献
Mazer, Thomas; Hileman, Fred D.; Noble, Roy W.; Brooks, Joseph J.
Analytical Chemistry, 1983 , vol. 55, # 1 p. 104 - 110
反应条件
potassium-sodium Reduction; dechlorination; Heating; Product distribution; Further Variations:Solvents;
参考文献
Miyoshi, Kumiko; Nishio, Takehiko; Yasuhara, Akio; Morita, Masatoshi
Chemosphere, 2000 , vol. 41, # 6 p. 819 - 824
反应条件
potassium-sodium Reduction; dechlorination; Heating; Product distribution; Further Variations:Solvents;
参考文献
Miyoshi, Kumiko; Nishio, Takehiko; Yasuhara, Akio; Morita, Masatoshi
Chemosphere, 2000 , vol. 41, # 6 p. 819 - 824