oxygen; palladium diacetate in dimethyl sulfoxide T=80°C; Heck Reaction; P=760.051 Torr; Molecular sieveInert atmosphere; ConcentrationReagent/catalystTemperature;

N,N'-dimethyl-(R)-1,1'-binaphthyldiamine-bis-2-pyridinecarboxyamide; trichlorosilane in dichloromethane T=0°C; 12 h; Inert atmosphere; optical yield given as percent eestereoselective reaction;

N,N'-dimethyl-(R)-1,1'-binaphthyldiamine-bis-2-pyridinecarboxyamide; trichlorosilane in dichloromethane T=0°C; 12 h; Inert atmosphere; optical yield given as percent eestereoselective reaction;

C17H26N2O2S; trichlorosilane in tetrachloromethane T=0°C; 24 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;