4-氟-Alpha-甲基苯乙烯合成路线 (共 27 条)
反应条件
ozone in hexane T=25°C; relative reaction rate;
参考文献
Murray, Robert W.; Iyanar, Kaliappan; Lee, Chung-Li; Chen, Jianxin
Journal of Organic Chemistry, 1995 , vol. 60, # 16 p. 5335 - 5336
反应条件
1: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; trimethylsilylazide; oxygen / acetonitrile / 36 h / 80 °C / 760.05 Torr / |Schlenk technique 2: potassium tert-butylate / dimethyl sulfoxide / 0.5 h 3: 16 h 4: water; sodium carbonate / |Reflux View Scheme
参考文献
Wang, Teng; Jiao, Ning
Journal of the American Chemical Society, 2013 , vol. 135, # 32 p. 11692 - 11695
反应条件
1: 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; trimethylsilylazide; oxygen / acetonitrile / 36 h / 80 °C / 760.05 Torr / |Schlenk technique 2: potassium tert-butylate / dimethyl sulfoxide / 0.5 h View Scheme
参考文献
Journal of the American Chemical Society, , vol. 135, # 32 p. 11692 - 11695
反应条件
standard free energy changes investigated; Thermodynamic data;
参考文献
Mishima, Masaaki; Arima, Kiyoshi; Usui, Satoshi; Fujio, Mizue; Tsuno, Yuho
Chemistry Letters, 1987 , p. 1047 - 1050
反应条件
methanol; formaldehyd; ammonium chloride
Erw. des Rktprod. mit konz. wss. Salzsaeure;
参考文献
Janssen et al.
Journal of Medicinal and Pharmaceutical Chemistry, 1959 , vol. 1, p. 281,284
反应条件
hydrogen; platinum(IV) oxide in ethanol
参考文献
Adcock,W. et al.
Journal of the American Chemical Society, 1975 , vol. 97, # 8 p. 2198 - 2205
参考文献
Ciba Specialty Chemicals Corporation
Patent: US6800676 B2, 2004 ;