5-溴-2,2′-联噻吩合成路线 （共 42 条）
反应条件
in tetrahydrofuran; water Suzuki Coupling; Reflux;
参考文献
Dalton Transactions, , vol. 42, # 3 p. 638 - 644
参考文献
Journal of Physical Chemistry, , vol. 94, # 15 p. 5761 - 5766
反应条件
trans-lt;Mo(N2)2(Ph2PCH2CH2PPh2)2gt; 4 h; Irradiation; Product distribution;
参考文献
Gazzetta Chimica Italiana, , vol. 114, # 5/6 p. 221 - 224
反应条件
1: 2-(5-bromothienyl)-2-thiophene With magnesium in tetrahydrofuran Inert atmosphereReflux; 2: N,N-dimethyl-formamide in tetrahydrofuran 3: With hydrogenchloride in tetrahydrofuran; water Cooling with ice;
参考文献
Deng, Huayun; Fang, Ye; He, Mingqian; Hu, Haibei; Niu, Weijun; Sun, Haiyan
Patent: US2012/22116 A1, 2012 ;
Location in patent: Page/Page column 55 ;
反应条件
1: dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; sodium carbonate; bis(dibenzylideneacetone)-palladium(0) / 1,4-dioxane; water / 36 h / Reflux 2: ethylenediamine / 1,4-dioxane; propan-1-ol; water / 24 h / Reflux View Scheme
参考文献
Murai, Norio; Miyano, Masayuki; Yonaga, Masahiro; Tanaka, Keigo
Organic Letters, 2012 , vol. 14, # 11 p. 2818 - 2821
反应条件
copper(l) iodide; sodium iodide; N-methyl-2-(methylamino)ethylamine T=105°C;
参考文献
Beilstein Journal of Organic Chemistry, , vol. 7, art. no. 7, p. 1499 - 1503
反应条件
potassium phosphate; 2-(dimethylamino)-ethanol; copper(l) iodide; copper T=80°C; 36 h;
参考文献
Lu, Zhikuan; Twieg, Robert J.
Tetrahedron, 2005 , vol. 61, # 4 p. 903 - 918
反应条件
1: 2-(5-bromothienyl)-2-thiophene With n-butyllithium in tetrahydrofuran T=-78 - 20°C; 1 h; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran T=-78°C; 12 h;
参考文献
GYEONGSANG NATIONAL UNIVERSITY INDUSTRIAL AND ACADEMIC COLLABORATION FOUNDATION
Patent: WO2008/120839 A1, 2008 ;
Location in patent: Page/Page column 42-43 ;
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in diethyl ether T=-20 - 20°C; 18.5 h;
参考文献
Rossi, Renzo; Carpita, Adriano; Ciofalo, Maurizio; Houben, Julien L.
Gazzetta Chimica Italiana, 1990 , vol. 120, p. 793 - 803
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether T=80°C; Suzuki cross-coupling reaction;
参考文献
Batista, Rosa M.F.; Costa, Susana P.G.; Belsley; Lodeiro, Carlos; Raposo, M. Manuela M.
Tetrahedron, 2008 , vol. 64, # 39 p. 9230 - 9238
