(2S,5S)-2,5-己二醇合成路线 （共 27 条）
反应条件
1: 75 percent / DIBAL, ZnBr2 / -78 °C 2: 75 percent / Raney Ni View Scheme
参考文献
Tetrahedron Letters, , vol. 35, # 29 p. 5297 - 5300
反应条件
1: With Saccharomyces cerevisiae L13 2: in water Kinetics; Reagent/catalyst;
参考文献
Katzberg, Michael; Wechler, Kerstin; Mueller, Marion; Duenkelmann, Pascal; Stohrer, Juergen; Hummel, Werner; Bertau, Martin
Organic and Biomolecular Chemistry, 2009 , vol. 7, # 2 p. 304 - 314
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 58, # 23 p. 6483 - 6485
反应条件
lipase (component B) from Candida antarctica immobilized on a macroporous polypropylic resin T=39°C; 4.5 h; other diols with C2-symmetry; resolution via lipase catalysed transesterification; Product distributionMechanism;
参考文献
Tetrahedron: Asymmetry, , vol. 4, # 5 p. 925 - 930
反应条件
mannose; Bacillus subtilis glucose dehydrogenase; Saccharomyces cerevisiae dehydrogenase Gre2p; nicotinamide adenine dinucleotide phosphate; magnesium chloride T=30°C; pH=10; aq. bufferEnzymatic reaction; Kinetics; stereoselective reaction;
参考文献
Mueller, Marion; Katzberg, Michael; Bertau, Martin; Hummel, Werner
Organic and Biomolecular Chemistry, 2010 , vol. 8, # 7 p. 1540 - 1550
反应条件
1: Et3N / CH2Cl2 / 1 h / 0 - 25 °C 2: 76 percent / tetrahydrofuran / 1.) -78 deg C, 1 h, 2.) 25 deg C, 16 h 3: 1.) Li / 1.) THF, 25 deg C, 10 h, 2.) THF, 25 deg C, 1 h View Scheme
参考文献
Burk; Feaster; Harlow
Tetrahedron Asymmetry, 1991 , vol. 2, # 7 p. 569 - 592
反应条件
1: 95 percent / CH2Cl2 / 18 h / 20 °C 2: 87 percent / thionyl chloride / CCl4 / 1 h / Heating 3: 65 percent / RuCl3; sodium periodate / CCl4; acetonitrile; H2O / 1 h / 25 °C 4: 86 percent / 96 h / 20 °C View Scheme
参考文献
Short, Robert P.; Kennedy, Robert M.; Masamune, Satoru
Journal of Organic Chemistry, 1989 , vol. 54, # 7 p. 1755 - 1756
