(2S,5S)-2,5-己二醇合成路线 （共 27 条）
反应条件
hydrogen; palladium on activated charcoal in ethanol P=38000 Torr; 2 h;
参考文献
Bach, Jordi; Berenguer, Ramon; Garcia, Jordi; Lopez, Marta; Manzanal, Judith; Vilarrasa, Jaume
Tetrahedron, 1998 , vol. 54, # 49 p. 14947 - 14962
反应条件
sodium hydroxide; D-glucose; baker's yeast (Saccharomyces cerevisiae) in water T=30°C; pH=6; 24 h;
参考文献
Braun, Wolfgang; Calmuschi, Beatrice; Haberland, Juergen; Hummel, Werner; Liese, Andreas; Nickel, Thomas; Stelzer, Othmar; Salzer, Albrecht
European Journal of Inorganic Chemistry, 2004 , # 11 p. 2235 - 2243
反应条件
(Ph)2SiH2; potassium carbonate; bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; (S,S)-2,2''-bis[(R)-1-(diethylphosphino)ethyl]-1,1'-biferrocene 1.) DME, -30 degC, 30 h; 2.) MeOH; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 36, # 29 p. 5239 - 5242
反应条件
hydrogenchloride; lt;NH2Et2gt;lt;lt;RuCl(S-BINAP)gt;2(μ-Cl)3gt;; hydrogen in methanol T=70°C; P=60900 Torr; 300 h; Yield given. Yields of byproduct given;
参考文献
Tetrahedron Asymmetry, , vol. 8, # 24 p. 4041 - 4045
反应条件
Rhodococcus ruber DSM 44541 in isopropyl alcohol T=30°C; pH=7.5; 48 h;
参考文献
European Journal of Organic Chemistry, , # 8 p. 1904 - 1909
反应条件
Candida antarctica lipase B in toluene T=20°C;
参考文献
Journal of Organic Chemistry, , vol. 68, # 6 p. 2216 - 2222
反应条件
sodium methylate in methanol T=0°C; electrochemical coupling, pH 5.38;
参考文献
Tetrahedron Asymmetry, , vol. 2, # 7 p. 569 - 592
反应条件
hydrogen; platinum on activated charcoal in methanol Yield given;
参考文献
Tetrahedron Letters, , vol. 38, # 6 p. 1091 - 1094
反应条件
1: 80 percent / Br2 / acetone; H2O / 3 h / -20 - 20 °C 2: 1.) BH3*SMe2, (R)-B-methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine, 2.) (-)-diethyl tartrate, titanium(IV) isopropoxide, t-BuOOH / 1.) THF, 0 deg C, 2.) CH2Cl2, isooctane, -20 deg C, 2 d 3: 81 percent / H2 / Pd/C / ethanol / 2 h / 38000 Torr View Scheme
参考文献
Tetrahedron, , vol. 54, # 49 p. 14947 - 14962
反应条件
1: 1.) BH3*SMe2, (R)-B-methyl-4,5,5-triphenyl-1,3,2-oxazaborolidine, 2.) (-)-diethyl tartrate, titanium(IV) isopropoxide, t-BuOOH / 1.) THF, 0 deg C, 2.) CH2Cl2, isooctane, -20 deg C, 2 d 2: 81 percent / H2 / Pd/C / ethanol / 2 h / 38000 Torr View Scheme
参考文献
Tetrahedron, , vol. 54, # 49 p. 14947 - 14962
