3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇合成路线 （共 16 条）
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
→
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
反应条件
thiourea in ethanol 72 h; Heating;
参考文献
Glennon, Jeremy D.
Analytical Chemistry, 1997 , vol. 69, # 12 p. 2207 - 2212
→
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
反应条件
tributylphosphine; water in tetrahydrofuran T=20°C; 9 h; Inert atmosphere;
参考文献
Coote, Susannah C.; Quenum, Seidjolo; Procter, David J.
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 14 p. 5104 - 5108
→
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇+
反应条件
sodium hydroxide in methanol Hydroformylation; Oxidative dimerization; 3 h; Heating;
参考文献
Naud; Calas; Blancou; Commeyras
Journal of Fluorine Chemistry, 2000 , vol. 104, # 2 p. 173 - 183
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
反应条件
sodium hydroxide 1.) EtOH, reflux; Multistep reaction;
参考文献
Journal of the American Chemical Society, , vol. 115, # 12 p. 5275 - 5283
→
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
反应条件
1.1: samarium diiodide / tetrahydrofuran / 0.33 h / 20 °C / Inert atmosphere 1.2: 80 °C / Inert atmosphere; Sealed tube 2.1: tributylphosphine; water / tetrahydrofuran / 9 h / 20 °C / Inert atmosphere View Scheme
参考文献
Organic and Biomolecular Chemistry, , vol. 9, # 14 p. 5104 - 5108
→
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
反应条件
1: 92 percent / benzoyl peroxide / 2 h / 92 - 101 °C 2: ethanol / 20 h / 79 °C 3: 62 percent / NaOH / H2O / 1 h / 78 - 80 °C View Scheme
参考文献
Journal of Fluorine Chemistry, , vol. 62, # 2-3 p. 217 - 241
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇+
→
反应条件
potassium carbonate in acetonitrile T=50°C;
参考文献
Christensen, Caspar; Clausen, Rasmus P.; Begtrup, Mikael; Kristensen, Jesper L.
Tetrahedron Letters, 2004 , vol. 45, # 43 p. 7991 - 7993
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
→
反应条件
potassium carbonate in acetonitrile T=50°C;
参考文献
Christensen, Caspar; Clausen, Rasmus P.; Begtrup, Mikael; Kristensen, Jesper L.
Tetrahedron Letters, 2004 , vol. 45, # 43 p. 7991 - 7993
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇+
→
反应条件
potassium carbonate in acetonitrile T=50°C;
参考文献
Christensen, Caspar; Clausen, Rasmus P.; Begtrup, Mikael; Kristensen, Jesper L.
Tetrahedron Letters, 2004 , vol. 45, # 43 p. 7991 - 7993
34143-74-33,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟-1-癸硫醇
→
反应条件
potassium carbonate in acetonitrile T=50°C;
参考文献
Christensen, Caspar; Clausen, Rasmus P.; Begtrup, Mikael; Kristensen, Jesper L.
Tetrahedron Letters, 2004 , vol. 45, # 43 p. 7991 - 7993
