5-(4-甲氧基苯基)-2-糠醛合成路线 （共 20 条）
反应条件
Tedicyp; potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)) in xylene T=130°C; Suzuki cross-coupling reaction; 20 h;
参考文献
Feuerstein, Marie; Doucet, Henri; Santelli, Maurice
Journal of Organometallic Chemistry, 2003 , vol. 687, # 2 p. 327 - 336
反应条件
tetrabutylammomium bromide; potassium acetate; tri-cyclo-hexyl-phosphine; palladium dichloride in N,N-dimethyl-formamide T=110°C; 10 h;
参考文献
McClure; Glover; McSorley; Millar; Osterhout; Roschangar
Organic letters, 2001 , vol. 3, # 11 p. 1677 - 1680
反应条件
hydrogenchloride; sodium nitrite 1.) H2O, 0-5 deg C, 0.5 h, 2.) H2O; Multistep reaction;
参考文献
Ciba-Geigy Corporation
Patent: US4559354 A1, 1985 ;
US 4559354 A
反应条件
triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in ethanol T=60°C; Suzuki cross-coupling reaction; 20 h;
参考文献
McClure; Roschangar; Hodson; Millar; Osterhout
Synthesis, 2001 , # 11 p. 1681 - 1685
反应条件
1: 2-(4-methoxy-phenyl)-furan With trichlorophosphate in 1,2-dichloro-ethane T=20°C; 0.0833333 h; 2: N,N-dimethyl-formamide in 1,2-dichloro-ethane T=80°C; 0.5 h; 3: T=0°C; 0.5 h; Product distribution / selectivity;
参考文献
Keio University
Patent: EP2022794 A1, 2009 ;
Location in patent: Page/Page column 22; 23 ;
反应条件
bis-triphenylphosphine-palladium(II) chloride; sodium carbonate in ethylene glycol dimethyl ether; ethanol; water T=50°C; Suzuki reaction; 1 h;
参考文献
Hosoya, Takamitsu; Aoyama, Hiroshi; Ikemoto, Takaaki; Kihara, Yasutaka; Hiramatsu, Toshiyuki; Endo, Makoto; Suzuki, Masaaki
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 5 p. 663 - 673
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=20°C; 24 h; Inert atmosphere;
参考文献
Kim, Seung-Hoi; Rieke, Reuben D.
Tetrahedron Letters, 2010 , vol. 51, # 19 p. 2657 - 2659
反应条件
bis-triphenylphosphine-palladium(II) chloride in ethylene glycol dimethyl ether T=50°C; Stille reaction; 2 h;
参考文献
Hosoya, Takamitsu; Aoyama, Hiroshi; Ikemoto, Takaaki; Kihara, Yasutaka; Hiramatsu, Toshiyuki; Endo, Makoto; Suzuki, Masaaki
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 5 p. 663 - 673
反应条件
bis-triphenylphosphine-palladium(II) chloride in acetonitrile T=20°C; Stille reaction; 0.5 h;
参考文献
Hosoya, Takamitsu; Aoyama, Hiroshi; Ikemoto, Takaaki; Kihara, Yasutaka; Hiramatsu, Toshiyuki; Endo, Makoto; Suzuki, Masaaki
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 5 p. 663 - 673
反应条件
palladium diacetate; caesium carbonate; triphenylphosphine in 1-methyl-pyrrolidin-2-one T=90°C; 1 h;
参考文献
Rao, Maddali L. N.; Awasthi, Dheeraj K.; Talode, Jalindar B.
Synlett, 2012 , vol. 23, # 13 p. 1907 - 1912
